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采用垂直地下水循环井技术的低扰动土地修复:在一家运营中的化工厂的首次商业应用。

Low-disturbance land remediation using vertical groundwater circulation well technology: The first commercial deployment in an operational chemical plant.

作者信息

Qiu Huiyang, Xu Jian, Yuan Yizhi, Alesi Eduard J, Liang Xin, Cao Benyi

机构信息

State Environmental Protection Key Laboratory of Soil Environmental Management and Pollution Control, Nanjing Institute of Environmental Sciences, Ministry of Ecology and Environment of China, Nanjing, Jiangsu, China; Department of Earth and Environmental Sciences, University of Waterloo, Waterloo, ON N2L 3G1, Canada.

State Environmental Protection Key Laboratory of Soil Environmental Management and Pollution Control, Nanjing Institute of Environmental Sciences, Ministry of Ecology and Environment of China, Nanjing, Jiangsu, China.

出版信息

Sci Total Environ. 2024 Sep 20;944:173804. doi: 10.1016/j.scitotenv.2024.173804. Epub 2024 Jun 5.

DOI:10.1016/j.scitotenv.2024.173804
PMID:38848922
Abstract

Soil and groundwater contamination by organic pollutants from chemical plants presents significant risks to both environmental and human health. We report a significant field trial where a chemical plant in operation showed soil and groundwater pollution, as verified by sampling and laboratory tests. While many remediation methods are effective, they often require the temporary shutdown of plant operations to install necessary equipment. This paper introduces a novel combination of low-disturbance contaminant remediation technologies, including groundwater circulation well (GCW), pump and treat (P&T), and in-situ chemical oxidation (ISCO) technologies, that can be applied on the premises of an active plant without halting production. The groundwater with dissolved contaminants is removed through P&T and GCW, while GCW enhances ISCO that focus on eliminating the remaining hard-to-pump contaminants. Results show: (1) after two years of remediation effort, the contaminant levels in soil and groundwater were significantly reduced; (2) the average concentration reduction rate of four contaminants, including 1,2-dichloroethane, methylbenzene, ethylbenzene, and M&P-xylene, exceeds 98 %; (3) the presented remediation strategy results in the improvement of remediation efficiency. Specifically, the concentration of 1,2-dichloroethane in observation wells dropped from 40,550.7 μg/L to 44.6 μg/L. This study offers a first-of-its-kind commercial deployment of a GCW-based remediation strategy in an active plant setting. Moreover, the combined remediation approach presented here can serve as a model for designing contaminant remediation projects that require minimal operational disruption.

摘要

化工厂排放的有机污染物对土壤和地下水造成的污染给环境和人类健康都带来了重大风险。我们报告了一项重要的现场试验,一家正在运营的化工厂存在土壤和地下水污染问题,这已通过采样和实验室测试得到证实。虽然许多修复方法都有效,但它们通常需要工厂暂时停产以安装必要设备。本文介绍了一种新型的低干扰污染物修复技术组合,包括地下水循环井(GCW)、抽提处理(P&T)和原位化学氧化(ISCO)技术,这些技术可在工厂正常生产的前提下应用,无需停产。通过P&T和GCW去除含有溶解污染物的地下水,而GCW增强了ISCO的效果,后者专注于消除残留的难抽提污染物。结果表明:(1)经过两年的修复工作,土壤和地下水中的污染物水平显著降低;(2)包括1,2 - 二氯乙烷、甲苯、乙苯和间/对二甲苯在内的四种污染物的平均浓度降低率超过98%;(3)所提出的修复策略提高了修复效率。具体而言,观测井中1,2 - 二氯乙烷的浓度从40550.7μg/L降至44.6μg/L。本研究首次在一家正常运营的工厂环境中进行了基于GCW的修复策略的商业应用。此外,本文提出的联合修复方法可为设计需要最小运营干扰的污染物修复项目提供范例。

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