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Influences of defective interphase and contact region among nanosheets on the electrical conductivity of polymer graphene nanocomposites.

作者信息

Zare Yasser, Munir Muhammad Tajammal, Rhee Kyong Yop

机构信息

Biomaterials and Tissue Engineering Research Group, Department of Interdisciplinary Technologies, Motamed Cancer Institute, Breast Cancer Research Center, ACECR, Tehran, Iran.

College of Engineering and Technology, American University of the Middle East, 54200, Egaila, Kuwait.

出版信息

Sci Rep. 2024 Jun 8;14(1):13210. doi: 10.1038/s41598-024-63981-1.


DOI:10.1038/s41598-024-63981-1
PMID:38851801
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11639709/
Abstract

In the current article, a defective interface is characterized by "D," representing the smallest diameter of nanosheets crucial for effective conduction transfer from the conductive filler to the medium, and by "ψ" as interfacial conduction. These parameters define the effective aspect ratio and operational volume fraction of graphene in the samples. The resistances of the graphene and polymer layer in contact zones are also considered to determine the contact resistance between adjacent nanosheets. Subsequently, a model for the tunneling conductivity of composites is proposed based on these concepts. This innovative model is validated by experimental data. Additionally, the effects of various factors on the conductivity of the composites and contact resistance are analyzed. Certain parameters such as filler concentration, graphene conductivity, interfacial conduction, and "D" do not affect the contact resistance due to the superconductivity of the nanosheets. However, factors like thin and large nanosheets, short tunneling distance (d), high interfacial conduction (ψ), low "D," and low tunnel resistivity (ρ) contribute to increased conductivity in nanocomposites. The maximum conductivity of 0.09 is obtained at d = 2 nm and ψ = 900 S/m, but d > 6 nm and ψ < 200 S/m produce an insulated sample. Additionally, the highest conductivity of 0.11 S/m is achieved with D = 100 nm and ρ = 100 Ω m, whereas the conductivity approaches 0 at D = 500 nm and ρ = 600 Ω m.

摘要

相似文献

[1]
Influences of defective interphase and contact region among nanosheets on the electrical conductivity of polymer graphene nanocomposites.

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[2]
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本文引用的文献

[1]
Effect of contact number among graphene nanosheets on the conductivities of tunnels and polymer composites.

Sci Rep. 2023-6-12

[2]
Progressing of a power model for electrical conductivity of graphene-based composites.

Sci Rep. 2023-1-28

[3]
An optical and electrochemical sensor based on L-arginine functionalized reduced graphene oxide.

Sci Rep. 2022-11-12

[4]
Microwave assisted synthesis of MnO nanograins intercalated into reduced graphene oxide layers as cathode material for alternative clean power generation energy device.

Sci Rep. 2022-11-9

[5]
Surface functionalization of graphene nanosheet with poly (L-histidine) and its application in drug delivery: covalent vs non-covalent approaches.

Sci Rep. 2022-11-9

[6]
Evaluation of dosimetric characteristics of a ternary nanocomposite based on High Density Polyethylene/Bismuth Oxide/Graphene Oxide for gamma-rays.

Sci Rep. 2022-11-5

[7]
Comparative removal of hazardous cationic dyes by MOF-5 and modified graphene oxide.

Sci Rep. 2022-9-12

[8]
An innovative model for conductivity of graphene-based system by networked nano-sheets, interphase and tunneling zone.

Sci Rep. 2022-9-7

[9]
Influence of the properties of different graphene-based nanomaterials dispersed in polycaprolactone membranes on astrocytic differentiation.

Sci Rep. 2022-8-4

[10]
Enhancing the mechanical properties and providing bioactive potential for graphene oxide/montmorillonite hybrid dental resin composites.

Sci Rep. 2022-6-17

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