He Cuiwei, Collins Steve, Murata Hideyuki
Opt Express. 2024 May 6;32(10):17152-17164. doi: 10.1364/OE.523128.
The use of fluorescent antennas in optical wireless communications (OWC) has been demonstrated previously, and it has been shown that it is an efficient method for enhancing receiver performance, providing both signal gain and a wide field of view (FoV). To achieve a high concentration gain at the receiver output, the selected fluorophores should have a high photoluminescence quantum yield (PLQY), limited overlap between their absorption and emission spectra, and emit light that can be efficiently detected. In addition, to support a high modulation bandwidth, the photoluminescence (PL) lifetime of the fluorophore needs to be short. In this paper, we propose a new fluorescent antenna architecture based on Förster resonance energy transfer (FRET). Our results show that, due to the photophysical interactions between the energy donor and energy acceptor, the use of FRET simultaneously increases PLQY and reduces PL lifetime. Additionally, employing FRET leads to an increased Stokes shift, ensuring that the emitted light has longer wavelengths, thus reducing self-absorption. This shift can also increase the efficiency with which the fluorescence is detected by a typical silicon (Si) photodetector. Consequently, our OWC results show that a new FRET-based antenna can achieve a significantly higher concentration gain and a wider transmission bandwidth than a conventional non-FRET antenna, leading to much higher data rates.
荧光天线在光无线通信(OWC)中的应用此前已得到证实,并且已表明它是一种提高接收器性能的有效方法,既能提供信号增益又能提供宽视场(FoV)。为了在接收器输出端实现高浓度增益,所选荧光团应具有高光致发光量子产率(PLQY),其吸收光谱和发射光谱之间的重叠有限,并且发射的光能够被有效检测。此外,为了支持高调制带宽,荧光团的光致发光(PL)寿命需要较短。在本文中,我们提出了一种基于Förster共振能量转移(FRET)的新型荧光天线架构。我们的结果表明,由于能量供体和能量受体之间的光物理相互作用,FRET的使用同时提高了PLQY并缩短了PL寿命。此外,采用FRET会导致斯托克斯位移增加,确保发射光具有更长的波长,从而减少自吸收。这种位移还可以提高典型硅(Si)光电探测器检测荧光的效率。因此,我们的OWC结果表明,基于FRET的新型天线能够比传统的非FRET天线实现显著更高的浓度增益和更宽的传输带宽,从而实现更高的数据速率。