具有可调光学性质的金@银核壳纳米棒的合成。

Synthesis of Au@Ag core-shell nanorods with tunable optical properties.

作者信息

Miryousefi Navid, Varmazyad Mahboubeh, Ghasemi Forough

机构信息

Department of Nanotechnology, Agricultural Biotechnology Research Institute of Iran (ABRII), Agricultural Research, Education, and Extension Organization (AREEO), Karaj, Iran.

Drug Discovery Institute, University of Pittsburgh, Pittsburgh, PA 15261, United States of America.

出版信息

Nanotechnology. 2024 Jul 12;35(39). doi: 10.1088/1361-6528/ad572b.

Abstract

The synthesis of noble metal nanostructures with adjustable optical properties is essential due to their potential applications in various fields such as imaging, (bio) sensors, and catalysis. In this study, Au@Ag core-shell nanorods were synthesized with tunable optical properties. The synthesis process includes a two-stage approach: first, gold nanorods were synthesized through seed-mediated growth, and in the second stage, these gold nanorods were used as seeds to synthesize Au@Ag core-shell nanorods through the silver deposition process. Tunable core-shell nanorods were produced by changing the concentration of silver ions, reducing agent, stabilizing agent, seeds, and buffer as well as pH and the reaction time. Transmission electron microscopy images demonstrated the formation of the Au@Ag core-shell nanorod structure. In addition, UV-visible spectroscopy revealed the peak height and its shift towards shorter wavelengths, demonstrating the tunable optical properties of the synthesized nanorods. Overall, in this study, we demonstrated the synthesis of Au@Ag core-shell nanorods with adjustable plasmonic optical properties that could be changed by precisely controlling the thickness of the silver shell on the surface of the gold core.

摘要

合成具有可调光学性质的贵金属纳米结构至关重要,因为它们在成像、(生物)传感器和催化等各个领域具有潜在应用。在本研究中,合成了具有可调光学性质的金@银核壳纳米棒。合成过程包括两阶段方法:首先,通过种子介导生长合成金纳米棒,在第二阶段,将这些金纳米棒用作种子,通过银沉积过程合成金@银核壳纳米棒。通过改变银离子、还原剂、稳定剂、种子、缓冲剂的浓度以及pH值和反应时间来制备可调核壳纳米棒。透射电子显微镜图像证实了金@银核壳纳米棒结构的形成。此外,紫外可见光谱显示了峰高及其向较短波长的移动,证明了合成纳米棒的可调光学性质。总体而言,在本研究中,我们展示了具有可调等离子体光学性质的金@银核壳纳米棒的合成,通过精确控制金核表面银壳的厚度可以改变这些性质。

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