Zhao Wendi, Huang Xiaoli, Zhang Zihan, Chen Su, Du Mingyang, Duan Defang, Cui Tian
Institute of High Pressure Physics, School of Physical Science and Technology, Ningbo University, Ningbo 315211, China.
State Key Laboratory of Superhard Materials, College of Physics, Jilin University, Changchun 130012, China.
Natl Sci Rev. 2023 Dec 7;11(7):nwad307. doi: 10.1093/nsr/nwad307. eCollection 2024 Jul.
Since the discovery of the high-temperature superconductors HS and LaH under high pressure, compressed hydrides have received extensive attention as promising candidates for room-temperature superconductors. As a result of current high-pressure theoretical and experimental studies, it is now known that almost all the binary hydrides with a high superconducting transition temperature ( ) require extremely high pressure to remain stable, hindering any practical application. In order to further lower the stable pressure and improve superconductivity, researchers have started exploring ternary hydrides and had many achievements in recent years. Here, we discuss recent progress in ternary hydrides, aiming to deepen the understanding of the key factors regulating the structural stability and superconductivity of ternary hydrides, such as structural motifs, bonding features, electronic structures, electron-phonon coupling, etc. Furthermore, the current issues and challenges of superconducting ternary hydrides are presented, together with the prospects and opportunities for future research.
自从在高压下发现高温超导体HS和LaH以来,压缩氢化物作为室温超导体的有前途的候选材料受到了广泛关注。由于目前的高压理论和实验研究,现在已知几乎所有具有高超导转变温度( )的二元氢化物都需要极高的压力才能保持稳定,这阻碍了任何实际应用。为了进一步降低稳定压力并提高超导性,研究人员已经开始探索三元氢化物,并且近年来取得了许多成果。在这里,我们讨论三元氢化物的最新进展,旨在加深对调节三元氢化物结构稳定性和超导性的关键因素的理解,如结构基序、键合特征、电子结构、电子-声子耦合等。此外,还介绍了超导三元氢化物当前存在的问题和挑战,以及未来研究的前景和机遇。