Suchat Sunisa, Boonrasri Siwarote
Faculty of Science and Industrial Technology, Prince of Songkla University Surat Thani Campus, Surat Thani 84000, Thailand.
Faculty of Engineering and Agro-Industry, Maejo University, Chiang Mai 50290, Thailand.
Polymers (Basel). 2024 May 24;16(11):1499. doi: 10.3390/polym16111499.
Common kitchen wraps like plastic and aluminum foil create significant environmental burdens. Plastic wrap, typically made from non-renewable fossil fuels, often ends up in landfills for centuries, breaking down into harmful microplastics. Aluminum foil, while effective, requires a large amount of energy to produce, and recycling it at home can be impractical due to food residue. A promising new alternative, low-nitrosamine rubber wrap film, aims to reduce waste by offering a reusable option compared to traditional single-use plastic wrap. The film is environmentally friendly, durable, and effective in sealing containers and keeping food fresh or crispy. The raw materials used to make the product were studied, namely fresh and concentrated natural rubber latex. No nitrosamines were found in either the fresh or concentrated latex, which is important as nitrosamines are known to be carcinogenic. The absence of nitrosamines in the raw materials suggests that the universal rubber wrap film is safe for use. In this study, the rubber formulation and properties of rubber used to make rubber wrap film were studied. The content of additives affecting the rubber properties was varied to find the optimum rubber formulation for making rubber wrap films. The rubber formulation with the least amount of chemicals that met the following criteria was selected: tensile strength of at least 15 MPa, elongation at break of at least 600%, and nitrosamine content below 6 ppm. It was found experimentally that the optimum rubber formulation for making a translucent rubber film had 0.7 phr zinc oxide and 1.0 phr sulfur. Performance tests revealed the rubber wrap film's superior sealing capabilities. Its elasticity allows for a tighter fit on containers, effectively conforming to various shapes and creating an optimal seal compared to plastic wrap and aluminum foil. The results of this study provide valuable information for developing a universal rubber wrap film that is safe with low nitrosamines.
常见的厨房保鲜膜,如塑料保鲜膜和铝箔,会造成重大的环境负担。塑料保鲜膜通常由不可再生的化石燃料制成,往往会在垃圾填埋场中存在数百年,分解成有害的微塑料。铝箔虽然有效,但生产过程需要大量能源,而且由于食物残渣,在家中回收利用并不实际。一种有前景的新替代品——低亚硝胺橡胶保鲜膜,旨在通过提供可重复使用的选择来减少浪费,相比传统的一次性塑料保鲜膜。这种保鲜膜环保、耐用,在密封容器和保持食物新鲜或酥脆方面效果良好。研究了用于制造该产品的原材料,即新鲜和浓缩天然橡胶乳胶。在新鲜乳胶和浓缩乳胶中均未发现亚硝胺,这一点很重要,因为亚硝胺已知具有致癌性。原材料中不含亚硝胺表明通用橡胶保鲜膜使用安全。在本研究中,对用于制造橡胶保鲜膜的橡胶配方和性能进行了研究。改变影响橡胶性能的添加剂含量,以找到制造橡胶保鲜膜的最佳橡胶配方。选择了符合以下标准且化学物质用量最少的橡胶配方:拉伸强度至少为15兆帕、断裂伸长率至少为600%、亚硝胺含量低于6 ppm。通过实验发现,制造半透明橡胶膜的最佳橡胶配方含有0.7份氧化锌和1.0份硫磺。性能测试表明橡胶保鲜膜具有卓越的密封能力。其弹性使其能更紧密地贴合容器,与塑料保鲜膜和铝箔相比,能有效贴合各种形状并形成最佳密封。本研究结果为开发一种低亚硝胺且安全的通用橡胶保鲜膜提供了有价值的信息。