Wang Wencan, Tian Wei, Chen Fang, Wang Jianyuan, Zhai Wei, Li Liang
MOE Key Laboratory of Materials Physics and Chemistry under Extraordinary Conditions, Northwestern Polytechnical University, Xi'an, 710072, China.
School of Physical Science and Technology, Jiangsu Key Laboratory of Frontier Material Physics and Devices, Center for Energy Conversion Materials & Physics (CECMP), Soochow University, Suzhou, 215006, China.
Adv Mater. 2024 Aug;36(33):e2404968. doi: 10.1002/adma.202404968. Epub 2024 Jun 26.
Color-selective photodetectors (PDs) play an indispensable role in spectral recognition, image sensing, and other fields. Nevertheless, complex filters and delicate optical paths in such devices significantly increase their complexity and size, which subsequently impede their integration in smart optoelectronic chips for universal applications. This work demonstrates the successful fabrication of filter-less color-selective perovskite PDs by integrating three perovskite units with different photoresponse on a single chip. The variation in photoresponse is attributed to different quantities of SnO nanoparticles, synthesized through controlled ultrasonic treatment on the surface of the electron transportation layer SnS, which selectively absorb short-wavelength light, thus increasing the relative transmittance of long-wavelength light and enhancing the photoresponse of the units to long wavelengths. By integrating any two units and deriving the formula for the wavelength to the responsivity ratio, a wavelength sensor is developed which can accurately identify incident light in the range of 400-700 nm with a minimum error <3 nm. Furthermore, the device integrating three units with different photoresponse can identify red, green and blue in polychromatic light to achieve color imaging with a relative error <6%. This work provides valuable insights into wavelength identification and color imaging of perovskite PDs.
颜色选择性光电探测器(PDs)在光谱识别、图像传感等领域发挥着不可或缺的作用。然而,此类器件中复杂的滤波器和精密的光路显著增加了其复杂性和尺寸,进而阻碍了它们在通用智能光电芯片中的集成。这项工作展示了通过在单个芯片上集成三个具有不同光响应的钙钛矿单元,成功制造出无滤波器的颜色选择性钙钛矿光电探测器。光响应的变化归因于在电子传输层SnS表面通过可控超声处理合成的不同数量的SnO纳米颗粒,这些纳米颗粒选择性地吸收短波长光,从而增加了长波长光的相对透过率,并增强了单元对长波长光的光响应。通过集成任意两个单元并推导波长与响应率比值的公式,开发出一种波长传感器,它能够在400 - 700 nm范围内准确识别入射光,最小误差<3 nm。此外,集成三个具有不同光响应单元的器件能够识别多色光中的红、绿、蓝,以实现相对误差<6%的彩色成像。这项工作为钙钛矿光电探测器的波长识别和彩色成像提供了有价值的见解。