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电氧化系统处理多氟烷基物质(PFAS)的综述:电氧化降解机制和电极材料。

A review of electrooxidation systems treatment of poly-fluoroalkyl substances (PFAS): electrooxidation degradation mechanisms and electrode materials.

机构信息

Key Laboratory of Bioelectrochemical Water Pollution Control Technology in Tangshan City, North China University of Science and Technology, Tangshan, People's Republic of China.

College of Civil and Architectural Engineering, North China University of Science and Technology, Tangshan, People's Republic of China.

出版信息

Environ Sci Pollut Res Int. 2024 Jun;31(30):42593-42613. doi: 10.1007/s11356-024-34014-1. Epub 2024 Jun 20.

Abstract

The prevalence of polyfluoroalkyls and perfluoroalkyls (PFAS) represents a significant challenge, and various treatment techniques have been employed with considerable success to eliminate PFAS from water, with the ultimate goal of ensuring safe disposal of wastewater. This paper first describes the most promising electrochemical oxidation (EO) technology and then analyses its basic principles. In addition, this paper reviews and discusses the current state of research and development in the field of electrode materials and electrochemical reactors. Furthermore, the influence of electrode materials and electrolyte types on the deterioration process is also investigated. The importance of electrode materials in ethylene oxide has been widely recognised, and therefore, the focus of current research is mainly on the development of innovative electrode materials, the design of superior electrode structures, and the improvement of efficient electrode preparation methods. In order to improve the degradation efficiency of PFOS in electrochemical systems, it is essential to study the oxidation mechanism of PFOS in the presence of ethylene oxide. Furthermore, the factors influencing the efficacy of PFAS treatment, including current density, energy consumption, initial concentration, and other parameters, are clearly delineated. In conclusion, this study offers a comprehensive overview of the potential for integrating EO technology with other water treatment technologies. The continuous development of electrode materials and the integration of other water treatment processes present a promising future for the widespread application of ethylene oxide technology.

摘要

多氟烷基和全氟烷基(PFAS)的普遍性是一个重大挑战,已经采用了各种处理技术来成功消除水中的 PFAS,最终目标是确保废水的安全处理。本文首先描述了最有前途的电化学氧化(EO)技术,然后分析了其基本原理。此外,本文还回顾和讨论了电极材料和电化学反应器领域的研究现状。此外,还研究了电极材料和电解质类型对降解过程的影响。在氧化过程中,电极材料的重要性已得到广泛认可,因此,目前的研究重点主要集中在开发创新的电极材料、设计优越的电极结构以及改进高效的电极制备方法上。为了提高电化学体系中 PFOS 的降解效率,研究 PFOS 在氧化过程中的氧化机制至关重要。此外,还明确了影响 PFAS 处理效果的因素,包括电流密度、能耗、初始浓度等参数。总之,本研究全面概述了将 EO 技术与其他水处理技术相结合的潜力。电极材料的不断发展和其他水处理工艺的整合为氧化技术的广泛应用带来了广阔的前景。

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