Wadhwa Gunchita Kaur, Late Dattatray J, Charhate Shrikant, Sankhyan Shashi Bhushan
Centre of Nanoscience and Nanotechnology, Amity School of Engineering and Technology, Amity University Maharashtra, Panvel, Mumbai, Maharashtra 410206, India.
Amity School of Engineering and Technology, Amity University Maharashtra, Panvel, Mumbai, Maharashtra 410206, India.
ACS Omega. 2024 Jun 12;9(25):26737-26761. doi: 10.1021/acsomega.3c10217. eCollection 2024 Jun 25.
Boron nitride (BN) with its 1D and 2D nano derivatives have gained immense popularity in both the field of research and applications. These nano derivatives have proved to be one of the most promising fillers which can be incorporated in polymers to form nanocomposites with excellent properties. These materials have been around for 25 years whereas significant research has been done in this field for only the past decade. There are many interesting properties which are imparted to the nanocomposites wherein thermal stability, large energy band gap, resistance to oxidation, excellent thermal conductivity, chemical inertness, and exceptional mechanical properties are just a few worthy of mention. Hexagonal boron nitride (h-BN) was selected as the parent material by most researchers reviewed in this paper through which 2D derivative Boron nitride nanosheets (BNNS) and 1D derivative Boron nitride nanotubes (BNNTs) are synthesized. This review will focus on the in-depth properties of h-BN and further will concisely focus on BNNS and BNNTs for their various properties. A detailed discussion of the addition of BNNS and BNNTs into polymers to form nanocomposites, their synthesis, properties, and applications is followed by a summary determining the most suitable synthesizing processes and the materials, keeping in mind the current challenges.
具有一维和二维纳米衍生物的氮化硼(BN)在研究和应用领域都广受欢迎。这些纳米衍生物已被证明是最有前途的填料之一,可与聚合物结合形成具有优异性能的纳米复合材料。这些材料已经存在了25年,而该领域的大量研究仅在过去十年才开展。纳米复合材料具有许多有趣的特性,其中热稳定性、大的能带隙、抗氧化性、优异的热导率、化学惰性和出色的机械性能只是其中几个值得一提的特性。本文综述中,大多数研究人员选择六方氮化硼(h-BN)作为母体材料,通过它合成二维衍生物氮化硼纳米片(BNNS)和一维衍生物氮化硼纳米管(BNNTs)。本综述将聚焦于h-BN的深入特性,并进一步简要关注BNNS和BNNTs的各种特性。在详细讨论将BNNS和BNNTs添加到聚合物中以形成纳米复合材料、它们的合成、特性及应用之后,将进行总结,确定最适合的合成工艺和材料,同时牢记当前面临的挑战。