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一种优化的阻抗匹配结构策略:通过静电纺丝法制备镶嵌镍纳米晶体的碳纳米纤维用于高性能微波吸收体。

An optimized impedance matching construction strategy: carbon nanofibers inlaid with Ni nanocrystals by electrospinning for high-performance microwave absorber.

作者信息

Zhang Danfeng, Gao Heng, Han Congai, Zeng Guoxun, Wu Qibai

机构信息

College of Innovation and Entrepreneurship, Guangdong University of Technology Guangzhou 510006 China

School of Materials and Energy, Guangdong University of Technology Guangzhou 510006 China.

出版信息

RSC Adv. 2024 Jul 1;14(29):20683-20690. doi: 10.1039/d4ra03367a. eCollection 2024 Jun 27.

Abstract

With the widespread use of electronic goods, solving electromagnetic pollution has become one of the new challenges. Higher requirements for microwave-absorbing materials (MAM) have emerged to address this issue. The composite of carbon nanofiber (CNF) and magnetic nanoparticles is the material that effectively absorbs microwaves. This paper fabricated Ni/C nanofibers using a combination of electrospinning and high-temperature carbonization. With 50 wt% paraffin wax, Ni/C nanofibers demonstrated optimal microwave absorption capabilities. With a thickness of 3 mm, the minimum RL value can reach -30.6 dB, and the effective absorption bandwidth is 5.96 GHz. By encapsulating Ni nanoparticles in carbon nanofibers, the synergic interaction of dielectric and magnetic losses effectively meets the need for constant attenuation and impedance matching, and effectively improves microwave-absorbing properties. Hence, Ni/C nanofibers are promising for MAM application with excellent MA performance.

摘要

随着电子产品的广泛使用,解决电磁污染已成为新的挑战之一。为解决这一问题,对微波吸收材料(MAM)提出了更高的要求。碳纳米纤维(CNF)与磁性纳米粒子的复合材料是有效吸收微波的材料。本文采用静电纺丝和高温碳化相结合的方法制备了Ni/C纳米纤维。在含有50 wt%石蜡的情况下,Ni/C纳米纤维表现出最佳的微波吸收能力。厚度为3 mm时,最小反射损耗(RL)值可达-30.6 dB,有效吸收带宽为5.96 GHz。通过将镍纳米粒子包裹在碳纳米纤维中,介电损耗和磁损耗的协同相互作用有效地满足了恒定衰减和阻抗匹配的需求,并有效提高了微波吸收性能。因此,Ni/C纳米纤维因其优异的微波吸收性能在微波吸收材料应用方面具有广阔前景。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/edc6/11215500/318eeb5f9d28/d4ra03367a-f1.jpg

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