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利用三亚乙基四胺功能化的MIP-206从废水中高效去除Pb(II)。

Utilizing triethylenetetramine-functionalized MIP-206 for highly efficient removal of Pb(II) from wastewater.

作者信息

Shilani Bizhan, Mehdipour Reza, Mousazadeh Behnam, Noruzi Yasin, Hosseini Seyednooroldin, Al-Saedi Hasan N, Mohealdeen Sura Mohammad

机构信息

Department of Petroleum Engineering, EOR Research Center, Omidiyeh Branch, Islamic Azad University, Omidiyeh, Iran.

Research and Development Department, Hetcochem Company, Tabriz, Iran.

出版信息

Sci Rep. 2024 Jul 6;14(1):15586. doi: 10.1038/s41598-024-66358-6.

Abstract

The global concern over heavy metal pollution necessitates urgent measures to safeguard human health and the environment. This study focuses on employing triethylenetetramine (TETA)-functionalized MIP-206-OH (TMIP-206) as an effective adsorbent for removing Pb(II) from wastewater. TMIP-206 was synthesized via a hydrothermal method followed by functionalization with TETA. Kinetic studies demonstrate that lead removal on TMIP-206 conforms to the pseudo-second-order model, indicating an efficient removal process. Experimental results reveal that TMIP-206 aligns with the Langmuir isotherm, exhibiting a maximum removal capacity of 267.15 mg/g for lead ions. The sorption efficiency of TMIP-206 for Pb ions remains stable across six cycles, with a reduction of less than 15%. Optimal adsorption performance is observed at a pH of 6. These findings underscore the potential of TMIP-206 as an alternative for adsorbing Pb(II) from aqueous environments, addressing the global challenge of heavy metal pollution. Future research should explore the scalability and long-term stability of TMIP-206-based adsorbents to enhance their practical applicability in diverse environmental contexts and contribute to broader strategies for mitigating heavy metal contamination.

摘要

全球对重金属污染的关注使得采取紧急措施保护人类健康和环境成为必要。本研究重点在于使用三亚乙基四胺(TETA)功能化的MIP - 206 - OH(TMIP - 206)作为从废水中去除Pb(II)的有效吸附剂。TMIP - 206通过水热法合成,随后用TETA进行功能化。动力学研究表明,TMIP - 206对铅的去除符合准二级模型,表明去除过程高效。实验结果表明,TMIP - 206符合朗缪尔等温线,对铅离子的最大去除容量为267.15 mg/g。TMIP - 206对Pb离子的吸附效率在六个循环中保持稳定,降低幅度小于15%。在pH为6时观察到最佳吸附性能。这些发现强调了TMIP - 206作为从水环境中吸附Pb(II)的替代品的潜力,应对了重金属污染这一全球挑战。未来的研究应探索基于TMIP - 206的吸附剂的可扩展性和长期稳定性,以提高其在不同环境背景下的实际适用性,并为减轻重金属污染的更广泛策略做出贡献。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28d9/11227518/482291735db0/41598_2024_66358_Fig1_HTML.jpg

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