Hsu Hsueh-Chuan, Wu Shih-Ching, Jian Zhong-Lin, Ho Wen-Fu
Department of Dental Technology and Materials Science, Central Taiwan University of Science and Technology, Taichung 40601, Taiwan.
Department of Chemical and Materials Engineering, National University of Kaohsiung, Kaohsiung 811726, Taiwan.
Materials (Basel). 2024 Jun 21;17(13):3062. doi: 10.3390/ma17133062.
Metal implants require an elastic modulus close to cortical bone (<30 GPa) to avoid stress shielding and ensure adequate load-bearing strength. The metastable β-type Ti-25Nb-8Sn alloy has a low elastic modulus (52 GPa), but its yield strength (<500 MPa) needs enhancement. This study enhances Ti-25Nb-8Sn's elastic admissible strain through cold rolling and aging heat treatments, investigating the microstructure's impact on mechanical and corrosion properties. The results show that lower-temperature aging (<450 °C) leads to ω-phase precipitation, yielding a 300% increase in yield strength (>1900 MPa). However, this also increases the elastic modulus (80 GPa), limiting the deformation ability. Higher-temperature aging (>500 °C) eliminates the ω phase, transforming it into α precipitates, resulting in a lower elastic modulus (65 GPa) and improved deformation ability, with substantial yield strength (>1000 MPa). In summary, the optimal process conditions are determined as 90% cold rolling followed by aging treatment at 550 °C. Under these conditions, Ti-25Nb-8Sn achieves the most suitable yield strength (1207 MPa) and high corrosion resistance, retaining a relatively low elastic modulus (64.7 GPa) and high elastic admissible strain (1.93%). This positions it as an ideal material for biomedical implants.
金属植入物需要弹性模量接近皮质骨(<30吉帕),以避免应力屏蔽并确保足够的承载强度。亚稳β型Ti-25Nb-8Sn合金具有较低的弹性模量(52吉帕),但其屈服强度(<500兆帕)需要提高。本研究通过冷轧和时效热处理提高Ti-25Nb-8Sn的弹性许用应变,研究微观结构对力学性能和腐蚀性能的影响。结果表明,较低温度时效(<450℃)会导致ω相析出,屈服强度提高300%(>1900兆帕)。然而,这也会增加弹性模量(80吉帕),限制变形能力。较高温度时效(>500℃)会消除ω相,将其转变为α析出物,导致弹性模量较低(65吉帕)且变形能力提高,同时屈服强度较高(>10吉帕)。总之,确定最佳工艺条件为90%冷轧后在550℃进行时效处理。在这些条件下,Ti-25Nb-8Sn获得了最合适的屈服强度(1207兆帕)和高耐腐蚀性,保持了相对较低的弹性模量(64.7吉帕)和高弹性许用应变(1.93%)。这使其成为生物医学植入物的理想材料。