Var Cansu, Palamutcu Sema
Department of Textile Engineering, Engineering Faculty, Pamukkale University, 20160 Denizli, Türkiye.
Polymers (Basel). 2024 Jun 27;16(13):1817. doi: 10.3390/polym16131817.
Alginate, categorized as a natural-based biodegradable polymer, stands out for its inherently exclusive properties. Although this unique polymer is widely processed using film, coating, and membrane technologies for different usage areas, textile applications are still limited. This study aims to compile promising approaches that will pave the way for the use of wet-spun alginate filaments in textile applications. In this regard, this study provides information about the molecular structure of alginate, the gel formation mechanism, and cross-linking using different techniques. Our literature review categorizes parameters affecting the mechanical properties of wet-spun alginate filaments, such as the effect of ion source and spinning dope concentration, needle diameter, temperature, and coagulants. Following this, a detailed and comprehensive literature review of the various approaches, such as use of additives, preparation of blended filaments, and grafted nanocrystal addition, developed by researchers to produce composite alginate filaments is presented. Additionally, studies concerning the use of different cations in the coagulation phase are reported. Moreover, studies about the functionalism of wet-spun alginate filaments have been offered.
海藻酸盐属于天然可生物降解聚合物,因其固有的独特性能而脱颖而出。尽管这种独特的聚合物广泛应用于不同领域的薄膜、涂层和膜技术加工,但在纺织应用方面仍受到限制。本研究旨在汇总一些有前景的方法,为湿纺海藻酸盐长丝在纺织应用中的使用铺平道路。在这方面,本研究提供了有关海藻酸盐分子结构、凝胶形成机制以及使用不同技术进行交联的信息。我们的文献综述对影响湿纺海藻酸盐长丝机械性能的参数进行了分类,如离子源和纺丝原液浓度、针头直径、温度以及凝固剂的影响。在此之后,对研究人员为生产复合海藻酸盐长丝而开发的各种方法,如添加剂的使用、混合长丝的制备和接枝纳米晶体的添加,进行了详细而全面的文献综述。此外,还报道了关于在凝固阶段使用不同阳离子的研究。此外,还提供了关于湿纺海藻酸盐长丝功能化的研究。