Islam Md Zahirul, Rahman Md Atikur, Gibbon Luke, Hall Eric, Ulven Chad A, La Scala John J
Mechanical Engineering Department, College of Engineering, North Dakota State University (NDSU), Dept 2490, P.O. Box 6050, Fargo, ND 58108, USA.
Combat Capabilities Development Command Army Research Laboratory, FCDD-RLW-MD, Aberdeen, MD 57401, USA.
Polymers (Basel). 2024 Jun 27;16(13):1828. doi: 10.3390/polym16131828.
Continuous carbon fiber-reinforced (CCFR) thermoset composites have received significant attention due to their excellent mechanical and thermal properties. The implementation of 3D printing introduces cost-effectiveness and design flexibility into their manufacturing processes. The light-assisted 3D printing process shows promise for manufacturing CCFR composites using low-viscosity thermoset resin, which would otherwise be unprintable. Because of the lack of shape-retaining capability, 3D printing of various shapes is challenging with low-viscosity thermoset resin. This study demonstrated an overshoot-associated algorithm for 3D printing various shapes using low-viscosity thermoset resin and continuous carbon fiber. Additionally, 3D-printed unidirectional composites were mechanically characterized. The printed specimen exhibited tensile strength of 390 ± 22 MPa and an interlaminar strength of 38 ± 1.7 MPa, with a fiber volume fraction of 15.7 ± 0.43%. Void analysis revealed that the printed specimen contained 5.5% overall voids. Moreover, the analysis showed the presence of numerous irregular cylindrical-shaped intra-tow voids, which governed the tensile properties. However, the inter-tow voids were small and spherical-shaped, governing the interlaminar shear strength. Therefore, the printed specimens showed exceptional interlaminar shear strength, and the tensile strength had the potential to increase further by improving the impregnation of polymer resin within the fiber.
连续碳纤维增强(CCFR)热固性复合材料因其优异的机械和热性能而备受关注。3D打印技术的应用为其制造过程带来了成本效益和设计灵活性。光辅助3D打印工艺有望使用低粘度热固性树脂制造CCFR复合材料,否则这些材料将无法打印。由于缺乏形状保持能力,使用低粘度热固性树脂进行各种形状的3D打印具有挑战性。本研究展示了一种与过冲相关的算法,用于使用低粘度热固性树脂和连续碳纤维进行各种形状的3D打印。此外,对3D打印的单向复合材料进行了力学表征。打印的试样表现出390±22MPa的拉伸强度和38±1.7MPa的层间强度,纤维体积分数为15.7±0.43%。孔隙分析表明,打印的试样总体孔隙率为5.5%。此外,分析显示存在许多不规则圆柱形的丝束内孔隙,这些孔隙决定了拉伸性能。然而,丝束间孔隙较小且呈球形,决定了层间剪切强度。因此,打印的试样表现出优异的层间剪切强度,并且通过改善聚合物树脂在纤维中的浸渍,拉伸强度有进一步提高的潜力。