Ludaš Dujmić Anja, Radičić Rafaela, Ercegović Ražić Sanja, Cingesar Ivan Karlo, Glogar Martinia, Jurov Andrea, Krstulović Nikša
Faculty of Textile Technology, University of Zagreb, Prilaz baruna Filipovića 28a, HR-10000 Zagreb, Croatia.
Institute of Physics, Bijenička cesta 46, HR-10000 Zagreb, Croatia.
Polymers (Basel). 2024 Jul 1;16(13):1883. doi: 10.3390/polym16131883.
With recent technological advances and the growing interest in environmentally friendly fiber production processes, the textile industry is increasingly turning to the spinning of filaments from recycled raw materials in the melt spinning process as the simplest method of chemical spinning of fibers. Such processes are more efficient because the desired active particles are melt-spun together with the polymer. The study investigates the melt spinning of recycled polyamide 6 (PA 6) fibers modified with zinc oxide nanoparticles (ZnO NPs) in concentrations ranging from 0.1 to 2.0 wt% of the polymer. The extrusion process was optimized under laboratory conditions. An analysis of the effectiveness of the nanoparticle distribution and chemical composition was performed using scanning electron microscopy (SEM) with energy-dispersive X-ray spectroscopy (EDS), differential scanning calorimetry (DSC), and Fourier transform infrared spectroscopy (FTIR). The results of the thermal analysis show an increase in the glass transition temperature of the extruded material from 50.97 °C (raw polymer) to 51.40 °C to 57.98 °C (polymer modified with ZnO NPs) and an increase in the crystallization point from 148.19 °C to a temperature between 175.61 °C and 178.16 °C, while the molar enthalpy (ΔHm) shows a decreasing trend from 65.66 Jg (raw polymer) to 48.23 Jg (PA 6 2.0% ZnO). The FTIR spectra indicate PA 6 polymer, with a characteristic peak at the wavelength 1466 cm, but pure ZnO and PA 6 blended with ZnO show a characteristic peak at 2322 cm. The distribution of nanoparticles on the fiber surface is more or less randomly distributed and the different size of NPs is visible. These results are confirmed by the EDS results, which show that different concentrations of Zn are present. The mechanical stability of the extruded polymer modified with NPs is not affected by the addition of ZnO NPs, although the overall results of strength (2.56-3.22 cN/tex) and modulus of elasticity of the polymer (28.83-49.90 cN/tex) are lower as there is no drawing process at this stage of the experiment, which certainly helps to increase the final strength of the fibers. The results indicate the potential of modification with ZnO NPs for further advances in sustainable fiber production.
随着近期技术的进步以及对环境友好型纤维生产工艺的兴趣日益浓厚,纺织行业越来越多地转向在熔体纺丝工艺中使用回收原材料纺制长丝,这是纤维化学纺丝中最简单的方法。此类工艺效率更高,因为所需的活性颗粒与聚合物一起进行熔体纺丝。该研究调查了用浓度为聚合物的0.1%至2.0%的氧化锌纳米颗粒(ZnO NPs)改性的回收聚酰胺6(PA 6)纤维的熔体纺丝。在实验室条件下对挤出工艺进行了优化。使用带有能量色散X射线光谱仪(EDS)的扫描电子显微镜(SEM)、差示扫描量热法(DSC)和傅里叶变换红外光谱法(FTIR)对纳米颗粒分布和化学成分的有效性进行了分析。热分析结果表明,挤出材料的玻璃化转变温度从50.97℃(未改性聚合物)升高到51.40℃至57.98℃(用ZnO NPs改性的聚合物),结晶点从148.19℃升高到175.61℃至178.16℃之间的某个温度,而摩尔焓(ΔHm)呈现出从65.66 J/g(未改性聚合物)降至48.23 J/g(PA 6含2.0% ZnO)的趋势。FTIR光谱表明存在PA 6聚合物,在波长1466 cm处有特征峰,但纯ZnO以及与ZnO混合的PA 6在2322 cm处有特征峰。纳米颗粒在纤维表面的分布或多或少是随机的,并且可以看到不同尺寸的纳米颗粒。EDS结果证实了这些结果,其表明存在不同浓度的锌。用纳米颗粒改性的挤出聚合物的机械稳定性不受ZnO NPs添加的影响,尽管聚合物的强度(2.56 - 3.22 cN/tex)和弹性模量(28.83 - 49.90 cN/tex)的总体结果较低,因为在实验的这个阶段没有拉伸过程,而拉伸肯定有助于提高纤维的最终强度。结果表明用ZnO NPs改性在可持续纤维生产的进一步发展方面具有潜力。