Karasoglu Mutlu, Öteyaka Mustafa Özgür, Yasa Evren, Tan Evren, Kuşhan Melih Cemal
Department of Mechanical Engineering, Faculty of Engineering, Eskişehir Technical University, Eskişehir 26555, Turkey.
Department of Mechanical Engineering, Faculty of Engineering and Architecture, Eskişehir Osmangazi University, Eskişehir 26480, Turkey.
ACS Omega. 2024 Jun 28;9(27):29904-29916. doi: 10.1021/acsomega.4c04218. eCollection 2024 Jul 9.
In this study, we investigated the effect of heat treatment (HT) and hot isostatic press (HIP) on the corrosion behavior of TiAl V, manufactured by electron beam melting (EBM) additive manufacturing. The preliminary results showed that the thermal process makes the columnar structure more pronounced and the α-lathe coarser compared to EBM. The β phase disappeared with the aging treatment and when increasing the HIP temperature treatment. According the open circuit potential ( ) behavior of samples, the HIP3 sample had performed more positive corrosion potential than rivals after 2 h of immersion probably due to equiaxed grain with coarser α-late and the absence of the β phase. In adverse, inferior corrosion behavior was observed for HIP1 because of a higher quantity of the β phase causing probably galvanic corrosion. The HIP process leads to a lower corrosion potential than EBM. At least one protective oxide layer formation was observed for all samples at the anodic branch, and the current density was lower for the HT3 sample. The microstructure analysis revealed the presence of the β-phase in the form of needle-like for the HT1 sample and HIP1 in the corroded area. Furthermore, the EDS line analysis showed the presence of aluminum with oxygen at the edge of the corrosion area for HIP1 suggesting aluminum plays a barrier against degradation. On the other hand, the HT1 showed higher impedance resistance due to the coarser α-lathe microstructure and well-defined β phase.
在本研究中,我们研究了热处理(HT)和热等静压(HIP)对通过电子束熔炼(EBM)增材制造制备的TiAlV腐蚀行为的影响。初步结果表明,与EBM相比,热加工使柱状结构更明显,α板条更粗大。随着时效处理以及HIP温度处理的升高,β相消失。根据样品的开路电位( )行为,浸泡2小时后,HIP3样品的腐蚀电位比其他样品更正,这可能是由于等轴晶粒、更粗大的α板条以及β相的缺失。相反,由于β相含量较高可能导致电偶腐蚀,HIP1的腐蚀行为较差。HIP工艺导致的腐蚀电位低于EBM。在阳极分支处,所有样品至少形成了一层保护性氧化层,HT3样品的电流密度较低。微观结构分析表明,在腐蚀区域,HT1样品和HIP1样品中存在针状β相。此外,EDS线分析表明,HIP1样品腐蚀区域边缘存在铝和氧,这表明铝起到了防止降解的屏障作用。另一方面,由于α板条微观结构更粗大且β相明确,HT1表现出更高的阻抗。