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通过电子束熔炼和选择性激光熔炼制造的用于体内植入的Ti-6Al-4V合金支架的耐腐蚀特性。

Corrosion resistance characteristics of a Ti-6Al-4V alloy scaffold that is fabricated by electron beam melting and selective laser melting for implantation in vivo.

作者信息

Zhao Bingjing, Wang Hong, Qiao Ning, Wang Chao, Hu Min

机构信息

Department of Stomatology, General Hospital of the PLA, Beijing, China; Department of Stomatology, The Second Affiliated Stomatological Hospital of Liaoning Medical University, China.

College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing, China.

出版信息

Mater Sci Eng C Mater Biol Appl. 2017 Jan 1;70(Pt 1):832-841. doi: 10.1016/j.msec.2016.07.045. Epub 2016 Jul 28.

Abstract

The purpose of this study is to determine the corrosion resistance of Ti-6Al-4V alloy fabricated with electron beam melting and selective laser melting for implantation in vivo. Ti-6Al-4V alloy specimens were fabricated with electron beam melting (EBM) and selective laser melting (SLM). A wrought form of Ti-6Al-4V alloy was used as a control. Surface morphology observation, component analysis, corrosion resistance experimental results, electrochemical impedance spectroscopy, crevice corrosion resistance experimental results, immersion test and metal ions precipitation analysis were processed, respectively. The thermal stability of EBM specimen was the worst, based on the result of open circuit potential (OCP) result. The result of electrochemical impedance spectroscopy indicated that the corrosion resistance of the SLM specimen was the best under the low electric potential. The result of potentiodynamic polarization suggested that the corrosion resistance of the SLM specimen was the best under the low electric potential (<1.5V) and EBM specimen was the best under the high electric potential (>1.5V).The crevice corrosion resistance of the EBM specimen was the best. The corrosion resistance of SLM specimen was the best, based on the result of immersion test. The content of Ti, Al and V ions of EBM, SLM and wrought specimens was very low. In general, the scaffolds that were fabricated with EBM and SLM had good corrosion resistance, and were suitable for implantation in vivo.

摘要

本研究的目的是确定通过电子束熔炼和选择性激光熔炼制造的用于体内植入的Ti-6Al-4V合金的耐腐蚀性。采用电子束熔炼(EBM)和选择性激光熔炼(SLM)制备了Ti-6Al-4V合金试样。使用锻造形式的Ti-6Al-4V合金作为对照。分别进行了表面形貌观察、成分分析、耐腐蚀性实验结果、电化学阻抗谱、缝隙腐蚀抗性实验结果、浸泡试验和金属离子沉淀分析。根据开路电位(OCP)结果,EBM试样的热稳定性最差。电化学阻抗谱结果表明,在低电位下SLM试样的耐腐蚀性最佳。动电位极化结果表明,在低电位(<1.5V)下SLM试样的耐腐蚀性最佳,而在高电位(>1.5V)下EBM试样的耐腐蚀性最佳。EBM试样的缝隙腐蚀抗性最佳。根据浸泡试验结果,SLM试样的耐腐蚀性最佳。EBM、SLM和锻造试样中Ti、Al和V离子的含量非常低。总体而言,通过EBM和SLM制造的支架具有良好的耐腐蚀性,适合体内植入。

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