Ni/Graphene Coating for Enhanced Corrosion Resistance of Metal Foam Flow Field in Simulated PEMFC Cathode Environment.

Metal foam flow field suffers serious corrosion issues in proton exchange membrane fuel cells due to its large surface area. Ni and Ni/graphene coatings are prepared under constant and gradient current modes, respectively, to improve the corrosion resistance. The effect of the electrodeposition current mode and the deposition mechanism is studied. Compared with Ni coating, Ni/graphene coating brings low corrosion current density and high coating resistance, effectively enhancing the stability of Ni foam in an acidic environment. Different from Ni coating with a single layer, Ni/graphene deposits have core-shell structure, with graphene coated on the surface of Ni nanoparticles. It is shown that graphene deposits cover the Ni particles during the electrodeposition, which protects nickel particles from agglomeration and forms an inert film on the surface of the porous structure. After an 8 h constant potential test, no significant pitting is observed on the surface of Ni/graphene coating, showing excellent anticorrosion performance. As to the effect of the deposition current mode, it is shown that more composite particles deposit on the upper layer under the gradient current mode, which brings denser protective film and fewer surface defects on the surface. Ni/graphene coating electrodeposited under a gradient current mode between 0 and 10 mA·cm exhibits the lowest corrosion current densities. The values at 50 and 80 °C are only 62.9 and 26.0% of those of uncoated Ni foam, respectively.