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给果汁通电:将应用电分析化学融入本科课程

Electrifying Fruit Juice: Integrating Applied Electroanalytical Chemistry into the Undergraduate Curriculum.

作者信息

Lima Dhésmon, Singh Vikram, Bulleeraz Karishma, Lussier Joey A, Kuss Sabine

机构信息

University of Manitoba, Department of Chemistry, Winnipeg R3T 2N2, Canada.

出版信息

J Chem Educ. 2024 Jun 11;101(7):2938-2946. doi: 10.1021/acs.jchemed.4c00419. eCollection 2024 Jul 9.

Abstract

Electroanalytical chemistry has been advanced through portable devices, providing methods and sensors for the detection of analytes with high sensitivity and accuracy. This subfield of electrochemistry has the potential to be utilized in industry and analytical quality control, in general. This results in an increasing demand for trained personnel, capable of operating benchtop and portable electroanalytical equipment. Although electrochemical techniques are routinely taught in theoretical undergraduate courses, they need to be more often incorporated into experimental didactic activities. Herein, we describe the application of an effective, hands-on, and low-maintenance experiment that can enhance the learning experience of electroanalytical methods and their use in industrial quality control settings. This activity is based on the detection of ascorbic acid (vitamin C) by employing cyclic voltammetry at unmodified glassy carbon electrodes (GCE) in real juice samples. This didactic experiment teaches students about the theoretical concepts of cyclic voltammetry, three-electrode cell setup, chemical reversibility, data treatment, and quantitative analysis. This teaching approach was conducted in a second-year analytical chemistry course and was easily adapted to social distancing measures imposed by the COVID-19 pandemic.

摘要

便携式设备推动了电分析化学的发展,为高灵敏度和高精度检测分析物提供了方法和传感器。一般来说,电化学的这个子领域有潜力应用于工业和分析质量控制。这导致对能够操作台式和便携式电分析设备的专业人员的需求不断增加。尽管电化学技术在本科理论课程中经常讲授,但它们需要更频繁地纳入实验教学活动。在此,我们描述了一个有效、实用且维护成本低的实验的应用,该实验可以增强电分析方法及其在工业质量控制环境中的应用的学习体验。该活动基于在未修饰的玻碳电极(GCE)上采用循环伏安法检测实际果汁样品中的抗坏血酸(维生素C)。这个教学实验向学生传授循环伏安法的理论概念、三电极电池设置、化学可逆性、数据处理和定量分析。这种教学方法在二年级分析化学课程中进行,并且很容易适应COVID-19大流行所实施的社交距离措施。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/69bb/11238731/b7d92bbc6052/ed4c00419_0003.jpg

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