Qin Jie, Lei Hong, Gao Chuanhua, Zheng Yuewen, Zhao Yating, Xia Wujiong
College of Chemical and Material Engineering, Quzhou University, Quzhou 324000, China.
State Key Lab of Urban Water Resource and Environment, School of Science, Harbin Institute of Technology (Shenzhen), Shenzhen, 518055, China.
Org Biomol Chem. 2024 Jul 31;22(30):6034-6044. doi: 10.1039/d4ob00876f.
Light-induced ligand-to-metal charge transfer (LMCT) has been utilized as a powerful strategy in various organic reactions. First-row transition metals, especially iron complexes, show good applications in this process. Fe(III)-Cl and Fe(III)-OR species are two key intermediates involved in the LMCT of iron complexes. This review highlights studies on LMCT of Fe(III)-OR species, including carboxylate-iron and alkoxy-iron species, in organic transformations. Reaction conditions, substrate scope and related mechanisms are discussed.
光诱导的配体到金属的电荷转移（LMCT）已被用作各种有机反应中的一种强大策略。第一排过渡金属，尤其是铁配合物，在这一过程中显示出良好的应用。Fe(III)-Cl和Fe(III)-OR物种是铁配合物LMCT过程中涉及的两个关键中间体。本综述重点介绍了Fe(III)-OR物种的LMCT研究，包括羧酸铁和烷氧基铁物种在有机转化中的研究。讨论了反应条件、底物范围和相关机理。
