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热剂废渣生物质和表面改性生物废料椰壳纤维增强生物复合材料——变废为宝。

Thermite frass biomass and surface modified biowaste coir fiber reinforced biocomposites-Conversion of waste to useful products.

机构信息

Department of Mechanical Engineering, Sree Buddha College of Engineering, Pattoor, Kerala, India.

Department of Mechanical Engineering, Sri Krishna College of Technology, Coimbatore, Tamil Nadu, India.

出版信息

Biopolymers. 2024 Nov;115(6):e23616. doi: 10.1002/bip.23616. Epub 2024 Jul 19.

Abstract

Polymer composites are known for its light weight and specific mechanical characteristics. This study examines sodium hydroxide (NaOH)-treated coir fiber, an agro-leftover, stuffed in a polyester matrix with termite frass powder, a bio-leftover for possible use in light-weight structural applications. Composite samples were made using compression molding and NaOH-treated coir fiber reinforced hybrid polymer composite (TCRHPC) with 40 wt% treated coir fiber and 1, 2, 3, and 4 wt% termite frass powder. TCRHPC samples mechanical, water captivation, tribological, and thermal properties were affected by termite frass powder wt%. The TCRHPC sample with 3 wt% termite frass powder has excellent mechanical properties, which improved by tensile (41.6%), flexural (28.57%), impact (43.7%), and hardness (18.84%) properties. With perfect water captivation and low weight increases in normal water (0.017 g), seawater (0.015 g), and NaOH solution (0.010 g), the identical composite sample with thermal stability up to 238°C also reduced wear mass by 5.27%. Conversely, filler agglomeration and heterogeneous dispersion in composite sample impair thermo-mechanical characteristics of TCRHPC containing 4 wt% termite frass powder. The bonding among polyester, treated coir fiber, and termite frass powder in composites were appraised with the aid of fractographic images of TCRHPC samples. The results show that TCRHPC material suits well for support structures requiring lesser weight.

摘要

聚合物复合材料以其重量轻和特定的机械特性而闻名。本研究探讨了经氢氧化钠(NaOH)处理的椰壳纤维,这是一种农业废料,填充在聚酯基体中,同时加入白蚁粪粉,这是一种生物废料,用于可能用于轻质结构应用。使用压缩成型制造复合材料样品,并使用 40wt%经处理的椰壳纤维和 1、2、3 和 4wt%白蚁粪粉填充的经处理的椰壳纤维增强混合聚合物复合材料(TCRHPC)。TCRHPC 样品的机械、水捕获、摩擦学和热性能受白蚁粪粉重量的影响。含有 3wt%白蚁粪粉的 TCRHPC 样品具有出色的机械性能,拉伸性能(提高 41.6%)、弯曲性能(提高 28.57%)、冲击性能(提高 43.7%)和硬度(提高 18.84%)都得到了提高。具有完美的水捕获能力,并且在正常水(0.017g)、海水(0.015g)和 NaOH 溶液(0.010g)中的重量增加率低,相同的复合材料样品在高达 238°C 的温度下也具有热稳定性,同时磨损质量减少了 5.27%。相反,含有 4wt%白蚁粪粉的复合材料中,填料团聚和不均匀分散会损害 TCRHPC 的热机械性能。借助 TCRHPC 样品的断口形貌图像评估了聚酯、经处理的椰壳纤维和白蚁粪粉在复合材料中的结合情况。结果表明,TCRHPC 材料非常适合需要更轻重量的支撑结构。

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