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螺环硼二吡咯的合成及光电性质

Synthesis and Optoelectronic Properties of Threaded BODIPYs.

作者信息

Hicguet Matthieu, Mongin Olivier, Leroux Yann R, Roisnel Thierry, Berrée Fabienne, Trolez Yann

机构信息

ISCR - UMR6226, École Nationale Supérieure de Chimie de Rennes, CNRS, ISCR - UMR6226, Univ Rennes, F-35000, Rennes, France.

出版信息

ChemistryOpen. 2024 Nov;13(11):e202400196. doi: 10.1002/open.202400196. Epub 2024 Jul 23.

DOI:10.1002/open.202400196
PMID:39041684
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12056918/
Abstract

We report on the synthesis of two new threaded BODIPYs 5 and 6 in good yields using boron as a gathering atom and a macrocycle with a 2,2'-biphenol unit. In addition to usual techniques, they were characterized by X-ray crystallography. Their electrochemical and optical properties were investigated. In particular, both compounds are highly emissive with photoluminescence quantum yields of 54 and 81 % respectively. In addition, they both show a high photostability.

摘要

我们报道了以硼作为聚集原子和带有2,2'-联苯酚单元的大环，高产率地合成了两种新型的穿线式氟硼二吡咯化合物5和6。除了常规技术外，还通过X射线晶体学对它们进行了表征。研究了它们的电化学和光学性质。特别地，这两种化合物均具有高发射性，其光致发光量子产率分别为54%和81%。此外，它们都表现出高的光稳定性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c195/12056918/65146fee38a1/OPEN-13-e202400196-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c195/12056918/a082549e8f3c/OPEN-13-e202400196-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c195/12056918/fd8428343cab/OPEN-13-e202400196-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c195/12056918/922f91e98218/OPEN-13-e202400196-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c195/12056918/307b9c966b56/OPEN-13-e202400196-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c195/12056918/ad2bba99974b/OPEN-13-e202400196-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c195/12056918/cb9e32759afe/OPEN-13-e202400196-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c195/12056918/b79ac0e99424/OPEN-13-e202400196-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c195/12056918/65146fee38a1/OPEN-13-e202400196-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c195/12056918/a082549e8f3c/OPEN-13-e202400196-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c195/12056918/fd8428343cab/OPEN-13-e202400196-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c195/12056918/922f91e98218/OPEN-13-e202400196-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c195/12056918/307b9c966b56/OPEN-13-e202400196-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c195/12056918/ad2bba99974b/OPEN-13-e202400196-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c195/12056918/cb9e32759afe/OPEN-13-e202400196-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c195/12056918/b79ac0e99424/OPEN-13-e202400196-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c195/12056918/65146fee38a1/OPEN-13-e202400196-g008.jpg

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