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利用双功能差分抽气气体滤光器对水和一氧化二氮的真空紫外吸收光谱

VUV absorption spectra of water and nitrous oxide by a double-duty differentially pumped gas filter.

作者信息

Bodi Andras, Knurr Jonas, Ascher Patrick, Hemberger Patrick, Bostedt Christoph, Al Haddad Andre

机构信息

Paul Scherrer Institute, 5232 Villigen-PSI, Switzerland.

出版信息

J Synchrotron Radiat. 2024 Sep 1;31(Pt 5):1257-1263. doi: 10.1107/S1600577524005423. Epub 2024 Jul 23.

Abstract

The differentially pumped rare-gas filter at the end of the VUV beamline of the Swiss Light Source has been adapted to house a windowless absorption cell for gases. Absorption spectra can be recorded from 7 eV to up to 21 eV photon energies routinely, as shown by a new water and nitrous oxide absorption spectrum. By and large, the spectra agree with previously published ones both in terms of resonance energies and absorption cross sections, but that of NO exhibits a small shift in the {\tilde{\bf D}} band and tentative fine structures that have not yet been fully described. This setup will facilitate the measurement of absorption spectra in the VUV above the absorption edge of LiF and MgF windows. It will also allow us to carry out condensed-phase measurements on thin liquid sheets and solid films. Further development options are discussed, including the recording of temperature-dependent absorption spectra, a stationary gas cell for calibration measurements, and the improvement of the photon energy resolution.

摘要

瑞士光源真空紫外光束线末端的差分抽运稀有气体滤光器已进行改装,用于容纳一个无窗气体吸收池。如一个新的水和一氧化二氮吸收光谱所示,通常可以在7 eV至高达21 eV的光子能量范围内记录吸收光谱。总体而言,这些光谱在共振能量和吸收截面方面与先前发表的光谱一致,但一氧化氮的光谱在{\tilde{\bf D}}带表现出小的位移以及尚未得到充分描述的暂定精细结构。这种设置将有助于在LiF和MgF窗口吸收边缘以上的真空紫外区域测量吸收光谱。它还将使我们能够对薄液膜和固体薄膜进行凝聚相测量。文中讨论了进一步的发展选项,包括记录温度相关的吸收光谱、用于校准测量的固定气体池以及光子能量分辨率的提高。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2436/11371026/5e73f5a16ed4/s-31-01257-fig1.jpg

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