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基于生物基纳米复合材料处理的可持续家居用品废织物的设计、表征及抗菌活性

Design, characterizations, and antimicrobial activity of sustainable home furnishing-based waste fabric treated using biobased nanocomposite.

作者信息

Swielam Eman M, Hussien Zeinab M, Hasanin Mohamed S

机构信息

Clothing and Knitting Industrial Research Department, Textile Research and Technology Institute, National Research Centre, Dokki, Cairo, 12622, Egypt.

Ready Made Garments Division, Industrial Arts Department, Faculty of Education, Helwan University, Cairo, Egypt.

出版信息

Bioresour Bioprocess. 2024 Jul 25;11(1):75. doi: 10.1186/s40643-024-00787-z.

Abstract

Clothing and textile industries are major contributors to environmental pollution including textile manufacturing through garment production, spinning, weaving, and dyeing. In this context, the sustainability textile industry is a big challenge and contributes to serving a large segment of society. Also, textile wastes could be used as a raw material for added-value products. Herein, in this study, recycling of residues fabric was treated with antimicrobial nanocomposite to reach the best use of exhausts and obtain multifunction products of aesthetic via the technical design of the waste raw materials. Besides, solving the unemployment problem by opening fields for small industry projects capable of producing high-value textile artifacts, especially when treated against microbes, can be applied to home furnishings. The waste fabric was treated via green synthesis nanocomposite based on chitosan and in situ prepared ZnONPs and cross-linked with tannic acid. The prepared nanocomposite was characterized using physicochemical analysis including attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR) and X-ray diffraction (XRD). Additionally, the nanocomposite and treated fabric topographical behavior were studied using scanning electron microscopy (SEM) attachment with energy dispersive X-ray analysis (EDX), and images were processed to evaluate the roughness structure. Additionally, high-resolution transmission electron microscopy (HR-TEM) and dynamic light scattering (DLS) were performed to ensure the size and stability of the nanocomposite. The obtained results affirmed the green synthesis of nanocomposite with a size around 130 nm, as well as the doped ZnONPs average size of 26 nm and treated waste fabric, performed a promising attraction between nanocomposite and fabric fibers. Moreover, the antimicrobial study observed excellent activity of nanocomposite against bacteria and unicellular fungi as well.

摘要

服装和纺织行业是环境污染的主要贡献者,包括通过服装生产、纺纱、织造和染色进行的纺织品制造。在这种背景下,可持续纺织工业是一项巨大挑战,并且有助于服务于社会的很大一部分。此外,纺织废料可作为增值产品的原材料。在此,在本研究中,用抗菌纳米复合材料处理残留织物的回收利用,以实现对废料的最佳利用,并通过对废原材料的技术设计获得具有美学价值的多功能产品。此外,通过为能够生产高价值纺织制品的小型工业项目开辟领域来解决失业问题,特别是当针对微生物进行处理时,可应用于家居用品。废织物通过基于壳聚糖的绿色合成纳米复合材料进行处理,并原位制备氧化锌纳米颗粒,然后与单宁酸交联。使用包括衰减全反射傅里叶变换红外光谱(ATR-FTIR)和X射线衍射(XRD)在内的物理化学分析对制备的纳米复合材料进行表征。此外,使用配备能量色散X射线分析(EDX)的扫描电子显微镜(SEM)研究纳米复合材料和处理后织物的表面形貌行为,并对图像进行处理以评估粗糙度结构。此外,进行了高分辨率透射电子显微镜(HR-TEM)和动态光散射(DLS)以确保纳米复合材料的尺寸和稳定性。获得的结果证实了纳米复合材料的绿色合成,其尺寸约为130nm,以及掺杂的氧化锌纳米颗粒的平均尺寸为26nm,处理后的废织物在纳米复合材料和织物纤维之间表现出良好的吸引力。此外,抗菌研究观察到纳米复合材料对细菌和单细胞真菌也具有优异的活性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fa17/11272763/c194e3ce7a23/40643_2024_787_Fig1_HTML.jpg

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