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锶放射性核素在改性钛酸钼复合材料上的吸附增强

Enhanced sorption of strontium radionuclides onto a modified molybdenum titanate composite.

作者信息

Abass M R, Ghaly M, Mekawy Zakaria A

机构信息

Hot Lab. Centre, Egyptian Atomic Energy Authority, PO 13759, Cairo, Egypt.

Hot Lab. Centre, Egyptian Atomic Energy Authority, PO 13759, Cairo, Egypt.

出版信息

Appl Radiat Isot. 2024 Oct;212:111447. doi: 10.1016/j.apradiso.2024.111447. Epub 2024 Jul 24.

Abstract

A study was conducted to investigate the sorption of Sr from aqueous solutions using a fabricated magnesium molybdenum titanate (MgMoTi) composite. The MgMoTi composites were synthesized through the co-precipitation technique and characterized using different analytical tools, including FT-IR, XRD, SEM, and EDX. The sorption studies focused on Sr and examined factors such as shaking time, pH, ionic strength, temperature, initial ion concentration, and saturation capacity. The results obtained from the study indicated that, under optimum sorption conditions, the saturation capacity for Sr onto S-4 and S-5 was determined to be 23.31 and 37.72 mg g, respectively. The sorption of Sr exhibited dependence on pH and ionic strength. The kinetics of the sorption process followed the pseudo-2nd-order model, while the thermodynamics revealed an endothermic and spontaneous nature. Desorption studies revealed that 0.1 M HCl was the most effective eluent for the complete recovery of Sr. Furthermore, the recycling results demonstrated the excellent recyclability of MgMoTi, suggesting its potential application as a sorbent for the removal of Sr from aqueous solutions. Overall, the study highlights MgMoTi as a promising composite with practical utility in the sorption of Sr from aqueous solutions.

摘要

开展了一项研究,以使用制备的钛酸镁钼(MgMoTi)复合材料研究从水溶液中吸附锶的情况。通过共沉淀技术合成了MgMoTi复合材料,并使用包括傅里叶变换红外光谱(FT-IR)、X射线衍射(XRD)、扫描电子显微镜(SEM)和能谱仪(EDX)在内的不同分析工具对其进行了表征。吸附研究聚焦于锶,并考察了振荡时间、pH值、离子强度、温度、初始离子浓度和饱和容量等因素。该研究获得的结果表明,在最佳吸附条件下,S-4和S-5对锶的饱和容量分别确定为23.31和37.72 mg/g。锶的吸附表现出对pH值和离子强度的依赖性。吸附过程的动力学遵循准二级模型,而热力学显示为吸热和自发性质。解吸研究表明,0.1 M盐酸是完全回收锶的最有效洗脱剂。此外,循环利用结果证明了MgMoTi具有出色的可循环利用性,表明其作为从水溶液中去除锶的吸附剂的潜在应用价值。总体而言,该研究突出了MgMoTi作为一种在从水溶液中吸附锶方面具有实际应用价值的有前景的复合材料。

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