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使用基于滑石粉制备的无机吸附剂从水溶液中吸附锶和铕离子的行为

Sorption behavior of strontium and europium ions from aqueous solutions using fabricated inorganic sorbent based on talc.

作者信息

Abass M R, Abou-Lilah R A, Hussein L M S

机构信息

Hot Laboratories, and Waste Management Centre, Egyptian Atomic Energy Authority, Cairo, 13759, Egypt.

出版信息

Sci Rep. 2024 Aug 26;14(1):19738. doi: 10.1038/s41598-024-69824-3.

Abstract

Sorption of Sr(II) and Eu(III) from aqueous solutions was studied using tin molybdate talc sorbent synthesized by the precipitation technique. The synthesized sorbent was characterized using different analytical tools, such as; FT-IR, SEM, XRD, XRF, TGA, and DTA. The sorption studies applied to Sr(II) and Eu(III) include the effects of shaking time, pH, concentrations, and saturation capacity. The sorption of Sr(II) and Eu(III) depends on pH, reaction kinetics obey the pseudo-2nd-order model, and the Langmuir model is better suited for the sorption isotherm. The thermodynamic parameters reflect an endothermic and spontaneous sorption process. Desorption studies showed that 0.1 M HCl was the best desorbing agent for the complete recovery of Sr(II) (96.8%) and Eu(III) (92.9%). Finally, the obtained data illustrates that the synthesized sorbent can be applied and used as an efficient sorbent for the sorption of Sr(II) and Eu(III) from aqueous solutions and can be used as a promising sorbent to remove Sr(II) and Eu(III).

摘要

采用沉淀法合成的钼酸锡滑石吸附剂,研究了其对水溶液中Sr(II)和Eu(III)的吸附性能。使用不同的分析工具对合成的吸附剂进行了表征,如傅里叶变换红外光谱(FT-IR)、扫描电子显微镜(SEM)、X射线衍射(XRD)、X射线荧光光谱(XRF)、热重分析(TGA)和差示热分析(DTA)。对Sr(II)和Eu(III)的吸附研究包括振荡时间、pH值、浓度和饱和容量的影响。Sr(II)和Eu(III)的吸附取决于pH值,反应动力学符合准二级模型,Langmuir模型更适合吸附等温线。热力学参数反映了一个吸热和自发的吸附过程。解吸研究表明,0.1 M HCl是完全回收Sr(II)(96.8%)和Eu(III)(92.9%)的最佳解吸剂。最后,所得数据表明,合成的吸附剂可作为一种高效吸附剂用于从水溶液中吸附Sr(II)和Eu(III),并可作为一种有前景的吸附剂用于去除Sr(II)和Eu(III)。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da54/11347636/ce2a49744405/41598_2024_69824_Fig1_HTML.jpg

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