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含硼氮苯的价键异构体

Boron-Nitrogen-Containing Benzene Valence Isomers.

作者信息

Ozaki Tomoya, Liu Shih-Yuan

机构信息

Department of Chemistry, Boston College, Chestnut Hill, Massachusetts, 02467-3860, USA.

出版信息

Chemistry. 2024 Oct 1;30(55):e202402544. doi: 10.1002/chem.202402544. Epub 2024 Sep 17.

DOI:10.1002/chem.202402544
PMID:39056374
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12092074/
Abstract

Benzene is one of the most ubiquitous structural motifs in chemistry. The valence isomers of benzene have also attracted synthetic chemists' attention due to their unique structures, bonding, and reactivity. We have been investigating boron-nitrogen-containing benzene valence isomers via photoisomerization of 1,2-azaborines. In this contribution, we summarize recent developments of these highly strained BN-heterocyclic compounds including their synthesis, characterization, proposed mechanism of formation, and their potential applications.

摘要

苯是化学中最普遍存在的结构单元之一。苯的价键异构体因其独特的结构、键合和反应活性也吸引了合成化学家的关注。我们一直在通过1,2-氮硼杂环戊二烯的光异构化来研究含硼氮的苯价键异构体。在本论文中，我们总结了这些高张力硼氮杂环化合物的最新进展，包括它们的合成、表征、推测的形成机理及其潜在应用。

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