Deng Changbo, Huang Qiuping, Fu Zhengping, Lu Yalin
Department of Materials Science and Engineering, University of Science and Technology of China, Hefei 230026, China.
Hefei National Research Center for Physical Sciences at the Microscale, Anhui Laboratory of Advanced Photon Science and Technology, University of Science and Technology of China, Hefei 230026, China.
Nanomaterials (Basel). 2024 Jul 15;14(14):1201. doi: 10.3390/nano14141201.
The ligand engineering of inorganic lead halide perovskite quantum dots (PQDs) is an indispensable strategy to boost their photoluminescence stability, which is pivotal for optoelectronics applications. CsPbX (X = Cl, Br, I) PQDs exhibit exceptional optical properties, including high color purity and tunable bandgaps. Despite their promising characteristics, environmental sensitivity poses a challenge to their stability. This article reviews the solution-based synthesis methods with ligand engineering. It introduces the impact of factors like humidity, temperature, and light exposure on PQD's instability, as well as in situ and post-synthesis ligand engineering strategies. The use of various ligands, including X- and L-type ligands, is reviewed for their effectiveness in enhancing stability and luminescence performance. Finally, the significant potential of ligand engineering for the broader application of PQDs in optoelectronic devices is also discussed.
无机卤化铅钙钛矿量子点(PQDs)的配体工程是提高其光致发光稳定性的必不可少的策略,这对于光电子应用至关重要。CsPbX(X = Cl、Br、I)PQDs表现出优异的光学性质,包括高色纯度和可调带隙。尽管它们具有令人期待的特性,但对环境的敏感性对其稳定性构成了挑战。本文综述了基于溶液的配体工程合成方法。介绍了湿度、温度和光照等因素对PQD不稳定性的影响,以及原位和合成后配体工程策略。综述了包括X型和L型配体在内的各种配体在提高稳定性和发光性能方面的有效性。最后,还讨论了配体工程在PQD在光电器件中更广泛应用的巨大潜力。