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互补多面体金属有机框架颗粒共组装成二元有序超结构。

Coassembly of Complementary Polyhedral Metal-Organic Framework Particles into Binary Ordered Superstructures.

作者信息

Meng Lingxin, Fonseca Javier, Sánchez-Naya Roberto, Ghadiri Amir Mohammad, Imaz Inhar, Maspoch Daniel

机构信息

Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC, and Barcelona Institute of Science and Technology Campus UAB, 08193 Bellaterra, Barcelona, Spain.

Departament de Química, Facultat de Ciències, Universitat Autònoma de Barcelona, 08193 Bellaterra, Spain.

出版信息

J Am Chem Soc. 2024 Aug 7;146(31):21225-21230. doi: 10.1021/jacs.4c07194. Epub 2024 Jul 26.

DOI:10.1021/jacs.4c07194
PMID:39058575
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11311218/
Abstract

Here we report the formation of a 3D NaCl-type binary porous superstructure coassembly of two colloidal polyhedral metal-organic framework (MOF) particles having complementary sizes, shapes, and charges. We employed a polymeric-attenuated Coulombic self-assembly approach, which also facilitated the coassembly of these MOF particles with spherical polystyrene particles to form 2D binary superstructures. Our results pave the way for using MOFs to create sophisticated superstructures comprising particles of various sizes, shapes, porosities, and chemical compositions.

摘要

在此，我们报道了由两个具有互补尺寸、形状和电荷的胶体多面体金属有机框架（MOF）颗粒形成的三维氯化钠型二元多孔超结构共组装体。我们采用了一种聚合物衰减库仑自组装方法，该方法还促进了这些MOF颗粒与球形聚苯乙烯颗粒的共组装，以形成二维二元超结构。我们的结果为利用MOF创建由各种尺寸、形状、孔隙率和化学成分的颗粒组成的复杂超结构铺平了道路。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/221b/11311218/29672e973558/ja4c07194_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/221b/11311218/fad5d9a7b026/ja4c07194_0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/221b/11311218/34e9278892b8/ja4c07194_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/221b/11311218/29672e973558/ja4c07194_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/221b/11311218/fad5d9a7b026/ja4c07194_0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/221b/11311218/34e9278892b8/ja4c07194_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/221b/11311218/29672e973558/ja4c07194_0003.jpg

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本文引用的文献

1
Space-tiled colloidal crystals from DNA-forced shape-complementary polyhedra pairing.通过DNA诱导的形状互补多面体配对形成的空间平铺胶体晶体。
Science. 2024 Jan 19;383(6680):312-319. doi: 10.1126/science.adj1021. Epub 2024 Jan 18.
2
Fabrication of Oriented Polycrystalline MOF Superstructures.取向多晶金属有机框架超结构的制备
Adv Mater. 2024 Jan;36(1):e2309645. doi: 10.1002/adma.202309645. Epub 2023 Nov 28.
3
Colloidal quasicrystals engineered with DNA.DNA 工程胶体准晶
Nat Mater. 2024 Mar;23(3):424-428. doi: 10.1038/s41563-023-01706-x. Epub 2023 Nov 2.
4
Assembly of Covalent Organic Frameworks into Colloidal Photonic Crystals.共价有机框架组装成胶体光子晶体。
J Am Chem Soc. 2023 Sep 20;145(37):20163-20168. doi: 10.1021/jacs.3c06265. Epub 2023 Sep 6.
5
Nanoparticle Brushes: Macromolecular Ligands for Materials Synthesis.纳米刷：用于材料合成的高分子配体。
Acc Chem Res. 2023 Jul 18;56(14):1931-1941. doi: 10.1021/acs.accounts.3c00160. Epub 2023 Jun 30.
6
Self-assembly of colloidal metal-organic framework (MOF) particles.胶体金属有机框架（MOF）颗粒的自组装。
Chem Soc Rev. 2023 Apr 3;52(7):2528-2543. doi: 10.1039/d2cs00858k.
7
Chiral assemblies of pinwheel superlattices on substrates.衬底上风车超晶格的手性组装体。
Nature. 2022 Dec;612(7939):259-265. doi: 10.1038/s41586-022-05384-8. Epub 2022 Nov 28.
8
Assembly of planar chiral superlattices from achiral building blocks.由非手性构建块组装平面手性超晶格。
Nat Commun. 2022 Jul 21;13(1):4207. doi: 10.1038/s41467-022-31868-2.
9
Low-dimensional assemblies of metal-organic framework particles and mutually coordinated anisotropy.金属有机骨架颗粒的低维组装与相互协调的各向异性。
Nat Commun. 2022 Jul 9;13(1):3980. doi: 10.1038/s41467-022-31651-3.
10
Metal-Organic Framework superstructures with long-ranged orientational order via E-field assisted liquid crystal assembly.通过电场辅助液晶组装制备具有长程取向有序的金属有机框架超结构。
J Colloid Interface Sci. 2022 Mar 15;610:1027-1034. doi: 10.1016/j.jcis.2021.11.151. Epub 2021 Nov 27.