Fonseca Javier, Meng Lingxin, Imaz Inhar, Maspoch Daniel
Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC and The Barcelona Institute of Science and Technology, Campus UAB, Bellaterra, 08193, Barcelona, Spain.
Departament de Química, Facultat de Ciències, Universitat Autònoma de Barcelona, 08193 Bellaterra, Spain.
Chem Soc Rev. 2023 Apr 3;52(7):2528-2543. doi: 10.1039/d2cs00858k.
Self-assembly of colloidal particles into ordered superstructures enables the development of novel advanced materials for diverse applications such as photonics, electronics, sensing, energy conversion, energy storage, diagnosis, drug or gene delivery, and catalysis. Recently, polyhedral metal-organic framework (MOF) particles have been proposed as promising colloidal particles to form ordered superstructures, based on their colloidal stability, size-tunability, rich polyhedral shapes, porosity and multifunctionality. In this review, we present a comprehensive overview of strategies for the self-assembly of colloidal MOF particles into ordered superstructures of different dimensionalities, highlighting some of their properties and applications, and sharing thoughts on the self-assembly of MOF particles.
胶体粒子自组装成有序超结构有助于开发用于多种应用的新型先进材料,如光子学、电子学、传感、能量转换、能量存储、诊断、药物或基因递送以及催化等。最近,基于其胶体稳定性、尺寸可调性、丰富的多面体形状、孔隙率和多功能性,多面体金属有机框架(MOF)粒子被认为是形成有序超结构的有前途的胶体粒子。在本综述中,我们全面概述了将胶体MOF粒子自组装成不同维度有序超结构的策略,重点介绍了它们的一些性质和应用,并分享了关于MOF粒子自组装的想法。