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后热处理对激光粉末床熔融增材制造的CuSn10腐蚀行为的影响

Influence of Post-Heat Treatment on Corrosion Behaviour of Additively Manufactured CuSn10 by Laser Powder Bed Fusion.

作者信息

Kremer Robert, Etzkorn Johannes, Khani Somayeh, Appel Tamara, Buhl Johannes, Palkowski Heinz

机构信息

Institute of Metallurgy, Clausthal University of Technology, Robert-Koch-Strasse 42, 38678 Clausthal-Zellerfeld, Germany.

Faculty of Mechanical Engineering, Dortmund University of Applied Sciences and Arts, Sonnenstr. 96, 44139 Dortmund, Germany.

出版信息

Materials (Basel). 2024 Jul 16;17(14):3525. doi: 10.3390/ma17143525.

Abstract

This study investigates the influence of heat treatments on the corrosion behaviour of CuSn10 tin bronze, additively manufactured using Laser Powder Bed Fusion (LPBF). LPBF enables the creation of finely structured, anisotropic microstructures, whose corrosion behaviour is not yet well understood. After production, specimens were heat-treated at 320 °C, 650 °C, and in a two-stage treatment at 800 °C and 400 °C, followed by hardness and microstructure analysis. Corrosion tests were conducted using linear polarisation, salt spray, and immersion tests. The results show that heat treatments at 320 °C and 650 °C have no significant effect on the corrosion rate, while the two-stage treatment shows a slight improvement in corrosion resistance. Differences in microstructure and hardness were observed, with higher treatment temperatures leading to grain growth and tin precipitates. The formation of a passive protective layer was detected after 30 h of OCP measurement. Results from other studies on corrosion behaviour were partially reproducible. Differences could be attributed to varying chemical compositions and manufacturing parameters. These findings contribute to the understanding of the effects of heat treatments on the corrosion resistance of additively manufactured tin bronze and provide important insights for future applications in corrosive environments.

摘要

本研究调查了热处理对采用激光粉末床熔融(LPBF)增材制造的CuSn10锡青铜腐蚀行为的影响。LPBF能够制造出结构精细、各向异性的微观结构,但其腐蚀行为尚未得到充分了解。生产后,试样分别在320℃、650℃下进行热处理,并在800℃和400℃下进行两阶段处理,随后进行硬度和微观结构分析。使用线性极化、盐雾和浸泡试验进行腐蚀测试。结果表明,320℃和650℃的热处理对腐蚀速率没有显著影响,而两阶段处理显示出耐腐蚀性略有提高。观察到微观结构和硬度存在差异,较高的处理温度导致晶粒长大和锡析出。在开路电位测量30小时后检测到形成了钝化保护层。其他关于腐蚀行为的研究结果部分可重现。差异可能归因于化学成分和制造参数的不同。这些发现有助于理解热处理对增材制造锡青铜耐腐蚀性的影响,并为未来在腐蚀性环境中的应用提供重要见解。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eceb/11278529/90332d7b5280/materials-17-03525-g001.jpg

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