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环保多功能屏蔽革命:单宁定制竹废料复合材料,具有吸波、阻燃和抗菌能力。

Eco-friendly versatile shielding revolution: Tannin tailored bamboo waste composite with wave-absorbing, flame retardancy, and antibacterial abilities.

机构信息

School of Chemical Science and Technology, Yunnan University, Kunming 650091, China.

School of Chemical Science and Technology, Yunnan University, Kunming 650091, China; BMI Center for Biomass Materials and Nanointerfaces, College of Biomass Science and Engineering, Sichuan University, Chengdu, Sichuan 610065, China.

出版信息

Int J Biol Macromol. 2024 Oct;277(Pt 3):134162. doi: 10.1016/j.ijbiomac.2024.134162. Epub 2024 Jul 26.

DOI:10.1016/j.ijbiomac.2024.134162
PMID:39069061
Abstract

The swift evolution of fifth-generation technology has intensified the need for lightweight, high-efficiency, and low-reflection multifunctional electromagnetic interference shielding materials, crucial in combating escalating electromagnetic pollution in complex application environments. To tackle these challenges, an innovative solution has emerged: a biocomposite crafted from discarded bamboo materials. This innovation incorporates a meticulously engineered functional coating composed of tannic acid, boric acid, and polyvinyl alcohol. Additionally, the integration of highly conductive TiCT (MXene) nanosheets onto the surface of bamboo powders enhances the EMI shielding efficiency of composites, achieving an impressive ∼40.9 dB. Meanwhile, significant improvements in mechanical reinforcement have been achieved, along with increases in the relative values of key performance indicators: tensile strength (89.8 %), tensile modulus (79.6 %), flexural strength (51.6 %), flexural modulus (35.1 %), and impact strength (45.4 %). Furthermore, the introduction of functional components grants the composite exceptional flame retardancy and antibacterial properties against both Gram-negative and Gram-positive bacteria. Beyond these strides, the utilization of bamboo waste as a composite pioneer a paradigm shift in waste utilization, converting refuse into invaluable resources.

摘要

第五代技术的迅速发展加剧了对轻量、高效、低反射多功能电磁干扰屏蔽材料的需求,在复杂应用环境中对抗不断升级的电磁污染至关重要。为了应对这些挑战,出现了一种创新的解决方案:一种由废弃竹材料制成的生物复合材料。该创新采用了精心设计的功能涂层,由单宁酸、硼酸和聚乙烯醇组成。此外,将高导电性 TiCT(MXene)纳米片整合到竹粉表面,提高了复合材料的 EMI 屏蔽效率,达到了令人印象深刻的约 40.9dB。同时,在力学增强方面也取得了显著的改善,关键性能指标的相对值得到了提高:拉伸强度(89.8%)、拉伸模量(79.6%)、弯曲强度(51.6%)、弯曲模量(35.1%)和冲击强度(45.4%)。此外,功能组件的引入赋予了复合材料出色的阻燃性和抗菌性能,可有效抵抗革兰氏阴性菌和革兰氏阳性菌。除此之外,利用竹废料作为复合材料的先驱开创了废物利用的范式转变,将废物转化为宝贵的资源。

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