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含硼化合物对涤棉混纺织物阻燃效果的分析

Analysis of the flame retardancy effect of boron-containing compound on polyester-cotton blended fabric.

作者信息

Hassan Mohammad Naim, Abdullah Tahrim Sadman, Mou Mehrin Beg, Towsif Hasin Raihan

机构信息

Department of Textile Engineering, Khulna University of Engineering & Technology, Khulna - 9203, Bangladesh.

出版信息

Heliyon. 2024 Jul 3;10(13):e34007. doi: 10.1016/j.heliyon.2024.e34007. eCollection 2024 Jul 15.

DOI:10.1016/j.heliyon.2024.e34007
PMID:39071651
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11277368/
Abstract

Flame-retardant finishing of textile materials is crucial for ensuring human safety and mitigating fire hazards. Though various textile fibers have inherent flame-resistant properties, cotton fiber has a higher affinity to burn. This research focused on developing non-durable FR treatments for cotton-rich polyester-cotton (T/C) blended products economically, using boron-containing compounds. Because of the high melting point use of borax on T/C fabric reduces the fabric's flammability. Boric acid was also used as an auxiliary substrate and Di-sodium hydrogen phosphate dihydrate was used for its cleaning and softening properties. Borax and boric acid create a layer of char when burned and stop the flame. We used the impregnation method for this finishing process. After the chemical finish on different types of T/C fabric, we completed different types of tests like flame retardant, LOI, SEM, breaking strength, drapability, crease recovery, and water vapor transmission tests, and found the desired properties. It increased the flame retardancy and crease recovery properties but the slight reduction of the fabric strength was noticed in case of excessive coating. Water vapor transmission property also reduced gradually with the increase of chemical concentration. Since the chemicals are available in the local market and lower in cost than common FR chemicals, it is more economical.

摘要

纺织材料的阻燃整理对于确保人类安全和减轻火灾危害至关重要。尽管各种纺织纤维具有固有的阻燃性能，但棉纤维具有较高的燃烧倾向。本研究着重于使用含硼化合物，经济地开发用于富含棉的涤棉（T/C）混纺产品的非耐久性阻燃处理方法。由于硼砂的高熔点，在T/C织物上使用硼砂可降低织物的可燃性。硼酸也用作辅助底物，而磷酸氢二钠二水合物因其清洁和软化性能而被使用。硼砂和硼酸在燃烧时会形成一层炭，从而阻止火焰蔓延。我们在此整理过程中采用了浸渍法。在对不同类型的T/C织物进行化学整理后，我们完成了不同类型的测试，如阻燃性、极限氧指数（LOI）、扫描电子显微镜（SEM）、断裂强度、悬垂性、折痕回复率和水蒸气透过率测试，并获得了预期的性能。它提高了阻燃性和折痕回复性能，但在涂层过多的情况下，织物强度略有下降。随着化学浓度的增加，水蒸气透过性能也逐渐降低。由于这些化学品在当地市场上可得且成本低于普通阻燃化学品，因此更具经济性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/23b1/11277368/066c5d79ca49/gr10.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/23b1/11277368/e7216ce35771/gr4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/23b1/11277368/0e42a88dfaeb/gr5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/23b1/11277368/cb9dfeb80552/gr6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/23b1/11277368/1bc8ab6d0eda/gr7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/23b1/11277368/6256d1e057af/gr8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/23b1/11277368/e39cd315e87e/gr9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/23b1/11277368/066c5d79ca49/gr10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/23b1/11277368/0d3fb56f5953/gr1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/23b1/11277368/3d097236ac3b/gr2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/23b1/11277368/6a062331971c/gr3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/23b1/11277368/e7216ce35771/gr4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/23b1/11277368/0e42a88dfaeb/gr5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/23b1/11277368/cb9dfeb80552/gr6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/23b1/11277368/1bc8ab6d0eda/gr7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/23b1/11277368/6256d1e057af/gr8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/23b1/11277368/e39cd315e87e/gr9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/23b1/11277368/066c5d79ca49/gr10.jpg

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