Embracing heterogeneous photocatalysis: evolution of photocatalysts in annulation of dimethylanilines and maleimides.

Recent advances in visible-light-promoted construction of tetrahydroquinolines from dimethylanilines and maleimides are documented. Homogeneous and heterogeneous photocatalytic systems, as well as the reaction mechanism, are emphasized. The mechanism of this photocatalytic annulation reaction is quite clear, , dimethylanilines and maleimides serve as the radical precursors and radical acceptors, respectively. This annulation reaction could serve as an excellent platform for evaluating novel oxidative heterogeneous photocatalytic systems, which could further inspire chemists in this field to develop more efficient photocatalytic systems. Significant opportunities are expected in the future for heterogeneous photocatalysis strategies.