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使用氧化锌纳米颗粒的高透射率、机械性能良好且热稳定的银纳米线网络

Highly Transmittance, Mechanical, Thermally Stable Silver Nanowires Network Using ZnO Nanoparticles.

作者信息

Trinh Ly Thi, To Thi Tu Linh, Ko Pyeongsam, Woo Kyoohee, Kwon Sin, Rho Jinsung, Youn Hongseok

机构信息

Mechanical Engineering Department, Hanbat National University, Yuseong-gu, Daejeon, 34158, South Korea.

Department of Advanced Battery Manufacturing Systems, Korea Institute of Machinery and Materials, Daejeon 156 Hwaam-dong, Daejeon, 34103, South Korea.

出版信息

Small. 2024 Nov;20(46):e2403702. doi: 10.1002/smll.202403702. Epub 2024 Aug 1.

DOI:10.1002/smll.202403702
PMID:39087377
Abstract

This research addresses challenges with silver nanowires (Ag NWs) as transparent conductive electrodes (TCEs) and heaters in commercial devices. Here, zinc oxide nanoparticles (ZnO NPs) are first reported as a protective layer for Ag NWs. Multi-physics simulations confirm enhanced thermal stability due to improved heat dissipation, temperature distribution, and thermal conductivity from ZnO. When Ag NWs are surrounded by air, heat transfers mainly through convection and radiation because of air's low conduction coefficient. Encasing Ag NWs in ZnO enhances heat transfer to the ZnO surface, accelerating cooling and dissipating more heat into the atmosphere via convection. The results show composite's efficiency in the Joule effect, maintaining a consistent temperature of 78 °C for 700 s after 500 bending cycles, a significant improvement over Ag NWs operating for only 5 s at 80 °C. Additionally, the composite film exhibited exceptional performance, including a sheet resistance of 9.8 Ω sq and an optical transmittance of 96.96 %, outperforming Ag NWs, which have a sheet resistance of 12 Ω sq and a transmittance of 94.11%. The combination of enhanced electrical, thermal, and mechanical stability, along with impressive optical properties, makes Ag NWs/ZnO NPs a promising candidate for transparent conductive electrode materials in various applications.

摘要

本研究探讨了银纳米线(Ag NWs)在商业设备中作为透明导电电极(TCEs)和加热器所面临的挑战。在此,首次报道了氧化锌纳米颗粒(ZnO NPs)作为Ag NWs的保护层。多物理场模拟证实,由于ZnO改善了散热、温度分布和热导率,从而提高了热稳定性。当Ag NWs被空气包围时,由于空气的低传导系数,热量主要通过对流和辐射传递。将Ag NWs包裹在ZnO中可增强向ZnO表面的热传递,加速冷却,并通过对流将更多热量散发到大气中。结果表明,该复合材料在焦耳效应方面具有高效性,在500次弯曲循环后,能在78°C的温度下保持700秒的恒定温度,这比仅在80°C下运行5秒的Ag NWs有显著改善。此外,复合薄膜表现出优异的性能,包括9.8Ω/sq的方块电阻和96.96%的光学透过率,优于方块电阻为12Ω/sq、透过率为94.11%的Ag NWs。增强的电学、热学和机械稳定性,以及令人印象深刻的光学性能,使Ag NWs/ZnO NPs成为各种应用中透明导电电极材料的有前途的候选者。

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