变色龙笼：由磷酸三（4-氨基苯基）前体配体合成的[FeL]四面体笼内阴离子、中性和阳离子客体物种的包封
Chameleonic Cages: Encapsulation of Anionic, Neutral, and Cationic Guest Species within [FeL] Tetrahedral Cages Synthesised from the tris(4-aminophenyl)phosphate pro-Ligand.
作者信息
Ward Jas S, Kruger Paul E
机构信息
MacDiarmid Institute for Advanced Materials and Nanotechnology, School of Physical and Chemical Sciences, University of Canterbury, 8041, Christchurch, New Zealand.
Current address: University of Jyvaskyla, Department of Chemistry, 40014, Jyväskylä, Finland.
出版信息
Chemistry. 2024 Dec 2;30(67):e202402547. doi: 10.1002/chem.202402547. Epub 2024 Oct 29.
An adaptable Fe(II) tetrahedral cage, [FeL][BF] (L=tris(4-(((E)-pyridin-2-ylmethylene)amino)phenyl) phosphate), has been synthesised via self-assembly. By modulating the orientation of its pendant P=O groups, the cage was found to be capable of encapsulating anionic, neutral, and cationic guests, which were confirmed in the solid state via single-crystal X-ray diffraction (SCXRD) and in solution by high-resolution mass spectroscopy (HR-MS), as well as by NMR (H, F, P) studies where possible.
通过自组装合成了一种可适配的Fe(II)四面体笼状化合物[FeL][BF]（L = 三(4 - (((E)-吡啶-2-基亚甲基)氨基)苯基)磷酸酯）。通过调节其悬垂P=O基团的取向，发现该笼状化合物能够包封阴离子、中性和阳离子客体，这在固态下通过单晶X射线衍射（SCXRD）得到证实，在溶液中通过高分辨率质谱（HR-MS）以及在可能的情况下通过NMR（H、F、P）研究得到证实。
Zotero 插件