通过插入极性 P[双键，长度为破折号]O 键对 [2+3] 有机分子笼进行空腔分隔和功能化。
Cavity partition and functionalization of a [2+3] organic molecular cage by inserting polar P[double bond, length as m-dash]O bonds.
机构信息
State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, P. R. China.
出版信息
Chem Commun (Camb). 2016 Jul 28;52(59):9267-70. doi: 10.1039/c6cc02801b. Epub 2016 Jun 29.
The cavity of a [2+3] organic molecular cage was partitioned and functionalized by inserting inner-directed P[double bond, length as m-dash]O bonds, which shows CO2 capture and CH4 exclusion due to the size-matching and polarity effects. Computational results demonstrate that the successful segmentation via polar P[double bond, length as m-dash]O bonds facilitates the CO2 molecules to reside selectively inside the cavity.
[2+3] 有机笼状分子的空腔通过插入指向内部的 P[双键，长度为破折号]O 键进行分隔和功能化，由于大小匹配和极性效应，这种 P[双键，长度为破折号]O 键表现出 CO2 捕获和 CH4 排斥性能。计算结果表明，通过极性 P[双键，长度为破折号]O 键的成功分段有利于 CO2 分子选择性地驻留在空腔内。
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