• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

关联单原子催化类芬顿反应中的活性位点与氧化物种。

Correlating active sites and oxidative species in single-atom catalyzed Fenton-like reactions.

作者信息

Miao Jie, Jiang Yunyao, Wang Xixi, Li Xue, Zhu Yuan, Shao Zongping, Long Mingce

机构信息

School of Environmental Science and Engineering, Nanjing Tech University Nanjing 211816 China.

State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University Nanjing 210009 China.

出版信息

Chem Sci. 2024 Jul 3;15(30):11699-11718. doi: 10.1039/d4sc02621g. eCollection 2024 Jul 31.

DOI:10.1039/d4sc02621g
PMID:39092108
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11290428/
Abstract

Single-atom catalysts (SACs) have gained widespread popularity in heterogeneous catalysis-based advanced oxidation processes (AOPs), owing to their optimal metal atom utilization efficiency and excellent recyclability by triggering reactive oxidative species (ROS) for target pollutant oxidation in water. Systematic summaries regarding the correlation between the active sites, catalytic activity, and reactive species of SACs have rarely been reported. This review provides an overview of the catalytic performance of carbon- and metal oxide-supported SACs in Fenton-like reactions, as well as the different oxidation pathways induced by the metal and non-metal active sites, including radical-based pathways (, ·OH and SO˙) and nonradical-based pathways ( O, high-valent metal-oxo species, and direct electron transfer). Thereafter, we discuss the effects of metal types, coordination environments, and spin states on the overall catalytic performance and the generated ROS in Fenton-like reactions. Additionally, we provide a perspective on the future challenges and prospects for SACs in water purification.

摘要

单原子催化剂（SACs）因其最佳的金属原子利用效率以及通过触发活性氧化物种（ROS）对水中目标污染物进行氧化而具有出色的可回收性，在基于多相催化的高级氧化过程（AOPs）中受到广泛关注。关于SACs的活性位点、催化活性和反应物种之间的相关性的系统总结鲜有报道。本综述概述了碳基和金属氧化物负载的SACs在类芬顿反应中的催化性能，以及金属和非金属活性位点诱导的不同氧化途径，包括基于自由基的途径（·OH和SO˙）和非自由基途径（O、高价金属氧物种和直接电子转移）。此后，我们讨论了金属类型、配位环境和自旋态对类芬顿反应中整体催化性能和产生的ROS的影响。此外，我们还展望了SACs在水净化方面未来面临的挑战和前景。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/772f/11290428/40a1f2ff9feb/d4sc02621g-f10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/772f/11290428/f47af3db6fa6/d4sc02621g-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/772f/11290428/db67b71e7d8a/d4sc02621g-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/772f/11290428/191148fdb356/d4sc02621g-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/772f/11290428/305900befa50/d4sc02621g-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/772f/11290428/048a27df79eb/d4sc02621g-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/772f/11290428/9e6571d3c644/d4sc02621g-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/772f/11290428/c495cb4ddaeb/d4sc02621g-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/772f/11290428/e8be90ffe643/d4sc02621g-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/772f/11290428/558ac12f986c/d4sc02621g-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/772f/11290428/40a1f2ff9feb/d4sc02621g-f10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/772f/11290428/f47af3db6fa6/d4sc02621g-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/772f/11290428/db67b71e7d8a/d4sc02621g-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/772f/11290428/191148fdb356/d4sc02621g-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/772f/11290428/305900befa50/d4sc02621g-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/772f/11290428/048a27df79eb/d4sc02621g-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/772f/11290428/9e6571d3c644/d4sc02621g-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/772f/11290428/c495cb4ddaeb/d4sc02621g-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/772f/11290428/e8be90ffe643/d4sc02621g-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/772f/11290428/558ac12f986c/d4sc02621g-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/772f/11290428/40a1f2ff9feb/d4sc02621g-f10.jpg

相似文献

1
Correlating active sites and oxidative species in single-atom catalyzed Fenton-like reactions.关联单原子催化类芬顿反应中的活性位点与氧化物种。
Chem Sci. 2024 Jul 3;15(30):11699-11718. doi: 10.1039/d4sc02621g. eCollection 2024 Jul 31.
2
How hetero-single-atom dispersion reconstructed electronic structure of carbon materials and regulated Fenton-like oxidation pathways.如何通过杂原子单原子分散重构碳材料的电子结构并调控类芬顿氧化途径。
Water Res. 2024 May 1;254:121417. doi: 10.1016/j.watres.2024.121417. Epub 2024 Mar 4.
3
Size-Dependent Catalysis in Fenton-like Chemistry: From Nanoparticles to Single Atoms.类芬顿化学中的尺寸依赖性催化：从纳米颗粒到单原子
Adv Mater. 2024 Jul;36(28):e2403965. doi: 10.1002/adma.202403965. Epub 2024 May 6.
4
Carbon-based single-atom catalysts in advanced oxidation reactions for water remediation: From materials to reaction pathways.用于水修复的高级氧化反应中的碳基单原子催化剂：从材料到反应途径
Eco Environ Health. 2023 Apr 25;2(2):47-60. doi: 10.1016/j.eehl.2023.04.002. eCollection 2023 Jun.
5
Single-atom catalysts based on Fenton-like/peroxymonosulfate system for water purification: design and synthesis principle, performance regulation and catalytic mechanism.基于类芬顿/过氧单硫酸盐体系的单原子催化剂用于水净化：设计与合成原理、性能调控及催化机制
Nanoscale. 2022 Oct 6;14(38):13861-13889. doi: 10.1039/d2nr02989h.
6
Recent advances in single-atom catalysts for advanced oxidation processes in water purification.单原子催化剂在水净化高级氧化工艺中的最新进展。
J Hazard Mater. 2021 Jun 15;412:125253. doi: 10.1016/j.jhazmat.2021.125253. Epub 2021 Jan 29.
7
Single atom catalyst-mediated generation of reactive species in water treatment.单原子催化剂介导的水处理中活性物种的生成
Chem Soc Rev. 2023 Nov 13;52(22):7673-7686. doi: 10.1039/d3cs00627a.
8
Metal Borides as Excellent Co-Catalysts for Boosted and Long-Lasting Fenton-like Reaction: Dual Co-Catalytic Centers of Metal and Boron.金属硼化物作为高效且持久类 Fenton 反应的助催化剂：金属和硼的双共催化中心。
Environ Sci Technol. 2023 Aug 22;57(33):12534-12545. doi: 10.1021/acs.est.3c03212. Epub 2023 Aug 9.
9
A critical review on correlating active sites, oxidative species and degradation routes with persulfate-based antibiotics oxidation.关于过硫酸盐基抗生素氧化中活性位点、氧化物种和降解途径的相关研究综述。
Water Res. 2023 May 15;235:119926. doi: 10.1016/j.watres.2023.119926. Epub 2023 Mar 27.
10
Atomic-Level Engineered Cobalt Catalysts for Fenton-Like Reactions: Synergy of Single Atom Metal Sites and Nonmetal-Bonded Functionalities.用于类芬顿反应的原子级工程钴催化剂：单原子金属位点与非金属键合官能团的协同作用
Adv Mater. 2024 Aug;36(32):e2401454. doi: 10.1002/adma.202401454. Epub 2024 Jun 10.

引用本文的文献

1
Design and Application of Atomically Dispersed Transition Metal-Carbon Cathodes for Triggering Cascade Oxygen Reduction in Wastewater Treatment.用于触发废水处理中串联氧还原的原子分散过渡金属-碳阴极的设计与应用
Molecules. 2025 Aug 4;30(15):3258. doi: 10.3390/molecules30153258.
2
Construction of Co-Modified MXene/PES Catalytic Membrane for Effective Separation and Degradation of Tetracycline Antibiotics in Aqueous Solutions.用于有效分离和降解水溶液中四环素抗生素的共修饰 MXene/PES 催化膜的构建。
Molecules. 2024 Oct 22;29(21):4995. doi: 10.3390/molecules29214995.

本文引用的文献

1
Size-Dependent Catalysis in Fenton-like Chemistry: From Nanoparticles to Single Atoms.类芬顿化学中的尺寸依赖性催化：从纳米颗粒到单原子
Adv Mater. 2024 Jul;36(28):e2403965. doi: 10.1002/adma.202403965. Epub 2024 May 6.
2
Sonocatalytic degradation of Bisphenol A from aquatic matrices over Pd/CeO nanoparticles: Kinetics study, transformation products, and toxicity.钯/二氧化铈纳米颗粒对水体中双酚A的声催化降解：动力学研究、转化产物及毒性
Sci Total Environ. 2024 Apr 1;919:170820. doi: 10.1016/j.scitotenv.2024.170820. Epub 2024 Feb 8.
3
Nanoconfinement-triggered oligomerization pathway for efficient removal of phenolic pollutants via a Fenton-like reaction.
纳米限域引发的低聚反应途径，通过类芬顿反应高效去除酚类污染物。
Nat Commun. 2024 Jan 31;15(1):917. doi: 10.1038/s41467-024-45106-4.
4
Plastic wastes-derived N-doped carbon nanotubes for efficient removal of sulfamethoxazole in high salinity wastewater via nonradical peroxymonosulfate activation.源自塑料废物的氮掺杂碳纳米管通过非自由基过一硫酸盐活化高效去除高盐度废水中的磺胺甲恶唑。
J Hazard Mater. 2024 Mar 5;465:133344. doi: 10.1016/j.jhazmat.2023.133344. Epub 2023 Dec 25.
5
Advances in Atomically Dispersed Metal and Nitrogen Co-Doped Carbon Catalysts for Advanced Oxidation Technologies and Water Remediation: From Microenvironment Modulation to Non-Radical Mechanisms.用于高级氧化技术和水修复的原子分散金属与氮共掺杂碳催化剂的进展：从微环境调控到非自由基机制
Small. 2024 May;20(22):e2308957. doi: 10.1002/smll.202308957. Epub 2023 Dec 19.
6
Single atom manganese catalyst boosting selective oxidation of alcohols with activated peroxymonosulfate.单原子锰催化剂促进活化过一硫酸盐对醇的选择性氧化
J Colloid Interface Sci. 2024 Feb 15;656:58-67. doi: 10.1016/j.jcis.2023.11.076. Epub 2023 Nov 15.
7
Atomically Dispersed Fe-N Site as a Conductive Bridge Enables Efficient and Stable Activation of Peroxymonosulfate: Active Site Renewal, Anti-Oxidative Capacity, and Pathway Alternation Mechanism.原子分散的铁氮位点作为导电桥促进过一硫酸盐的高效稳定活化：活性位点更新、抗氧化能力及途径交替机制
Environ Sci Technol. 2023 Dec 12;57(49):20929-20940. doi: 10.1021/acs.est.3c06229. Epub 2023 Nov 13.
8
Single atom catalyst-mediated generation of reactive species in water treatment.单原子催化剂介导的水处理中活性物种的生成
Chem Soc Rev. 2023 Nov 13;52(22):7673-7686. doi: 10.1039/d3cs00627a.
9
A Universal Electrochemical Synthetic Strategy for the Direct Assembly of Single-Atom Catalysts.一种用于直接组装单原子催化剂的通用电化学合成策略。
Adv Sci (Weinh). 2023 Dec;10(34):e2304656. doi: 10.1002/advs.202304656. Epub 2023 Oct 12.
10
Highly selective synthesis of surface Fe=O with nanoscale zero-valent iron and chlorite for efficient oxygen transfer reactions.利用纳米级零价铁和亚氯酸盐高度选择性合成表面Fe=O用于高效氧转移反应。
Proc Natl Acad Sci U S A. 2023 Sep 19;120(38):e2304562120. doi: 10.1073/pnas.2304562120. Epub 2023 Sep 11.