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Ag/g-CN/CoNi-LDH 纳米复合材料光降解能力的提高比较:水处理中的光催化活性。

A comparison increasing the photodegradation power of a Ag/g-CN /CoNi-LDH nanocomposite: Photocatalytic activity toward water treatment.

机构信息

Department of Chemical Engineering, Waterloo Institute for Nanotechnology (WIN), 200 University Ave W, Waterloo, ON N2L 3G1, Canada.

Department of Chemistry, Shahreza Branch, Islamic Azad University, 86145-311, Iran.

出版信息

J Environ Sci (China). 2025 Feb;148:437-450. doi: 10.1016/j.jes.2023.09.006. Epub 2023 Sep 14.

Abstract

For environmental applications, it is crucial to rationally design and synthesize photocatalysts with positive exciton splitting and interfacial charge transfer. Here, a novel Ag-bridged dual Z-scheme Ag/g-CN/CoNi-LDH plasmonic heterojunction was successfully synthesized using a simple method, with the goal of overcoming the common drawbacks of traditional photocatalysts such as weak photoresponsivity, rapid combination of photo-generated carriers, and unstable structure. These materials were characterized by XRD, FT-IR, SEM, TEM UV-Vis/DRS, and XPS to verify the structure and stability of the heterostructure. The pristine LDH, g-CN and Ag/g-CN/CoNi-LDH composite were investigated as photocatalysts for water remediation, an environmentally motivated process. Specifically, the photocatalytic degradation of tetracycline was studied as a model reaction. The performance of the supports and composite catalyst were determined by evaluating both the degradation and adsorption phenomenon. The influence of several experimental parameters such as catalyst loading, pH, and tetracycline concentration were evaluated. The current study provides important data for water treatment and similar environmental protection applications.

摘要

对于环境应用而言,合理设计和合成具有正激子分裂和界面电荷转移的光催化剂至关重要。在这里,我们采用一种简单的方法成功合成了一种新型的 Ag 桥联双 Z 型 Ag/g-CN/CoNi-LDH 等离子体异质结,旨在克服传统光催化剂的常见缺点,例如光响应性弱、光生载流子的快速复合和不稳定的结构。通过 XRD、FT-IR、SEM、TEM、UV-Vis/DRS 和 XPS 对这些材料进行了表征,以验证异质结构的结构和稳定性。将原始 LDH、g-CN 和 Ag/g-CN/CoNi-LDH 复合材料作为水修复的光催化剂进行了研究,这是一个具有环境驱动力的过程。具体而言,研究了光催化降解四环素作为模型反应。通过评估降解和吸附现象来确定载体和复合催化剂的性能。评估了催化剂负载量、pH 值和四环素浓度等几个实验参数的影响。本研究为水处理和类似的环境保护应用提供了重要数据。

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