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超声驱动压电催化剂 WS/BiWO 异质结复合材料降解有机污染物。

Ultrasonic-driven degradation of organic pollutants using piezoelectric catalysts WS/BiWO heterojunction composites.

机构信息

College of Optical and Electronic Technology, China Jiliang University, Hangzhou, 310018, China.

College of Modern Science and Technology, China Jiliang University, Yiwu, 322002, China.

出版信息

Chemosphere. 2024 Sep;364:143008. doi: 10.1016/j.chemosphere.2024.143008. Epub 2024 Aug 2.

Abstract

Water pollution has been made worse by the widespread use of organic dyes and their discharge, which has coincided with the industry's rapid development. Piezoelectric catalysis, as an effective wastewater purification method with promising applications, can enhance the catalyst activity by collecting tiny vibrations in nature and is not limited by sunlight. In this work, we designed and synthesized intriguing WS/BiWO heterojunction nanocomposites, investigated their shape, structure, and piezoelectric characteristics using a range of characterization techniques, and used ultrasound to accelerate the organic dye Rhodamine B (RhB) degradation in wastewater. In comparison to the pristine monomaterials, the results demonstrated that the heterojunction composites demonstrated excellent degradation and stability of RhB under ultrasonic circumstances. The existence of heterojunctions and the internal piezoelectric field created by ultrasonic driving work in concert to boost catalytic performance, and the organic dye's rate of degradation is further accelerated by the carriers that are mutually transferred between the composites.

摘要

水污染因有机染料的广泛应用及其排放而恶化,这与工业的快速发展恰好吻合。压电催化作为一种有效的废水净化方法,具有广阔的应用前景,它可以通过收集自然界中的微小振动来提高催化剂的活性,并且不受阳光的限制。在这项工作中,我们设计并合成了有趣的 WS/BiWO 异质结纳米复合材料,使用一系列的表征技术研究了它们的形状、结构和压电特性,并利用超声波加速废水中的有机染料罗丹明 B(RhB)的降解。与原始的单材料相比,结果表明,在超声条件下,异质结复合材料对 RhB 具有优异的降解和稳定性。异质结的存在和超声驱动产生的内电场协同作用,提高了催化性能,而载体在复合材料之间的相互转移进一步加速了有机染料的降解速率。

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