Dutta Jhuma, Yadav Nitin, Bhatt Pooja, Kaur Kuljeet, Gómez Daniel E, George Jino
Indian Institute of Science Education and Research (IISER) Mohali, Punjab 140306, India.
School of Science, RMIT University, Melbourne, Victoria 3000, Australia.
J Phys Chem Lett. 2024 Aug 15;15(32):8211-8217. doi: 10.1021/acs.jpclett.4c01511. Epub 2024 Aug 5.
We leveraged strong light-matter coupling, a quantum process generating hybridized states, to prepare phototransistors using donor-acceptor pairs that transfer energy via Rabi oscillations. In a prototype experiment, we used a cyanine J-aggregate (TDBC; donor) and MoS monolayer (acceptor) in a field effect transistor cavity to study photoresponsivity. Energy migrates through the newly formed polaritonic ladder, with enhanced device efficiency when the cavity is resonant with donors. A theoretical model based on the time-dependent Schrödinger equation helped interpret results, with polaritonic states acting as a strong energy funnel to the MoS monolayer. These findings suggest novel applications of strong light-matter coupling in quantum materials.
我们利用强光与物质耦合这一产生杂化态的量子过程,通过经由拉比振荡转移能量的供体 - 受体对来制备光电晶体管。在一个原型实验中,我们在场效应晶体管腔中使用了一种花菁J - 聚集体(TDBC;供体)和二硫化钼单层(受体)来研究光响应性。能量通过新形成的极化激元阶梯迁移,当腔与供体共振时,器件效率得到提高。基于含时薛定谔方程的理论模型有助于解释结果,极化激元态充当了通向二硫化钼单层的强大能量漏斗。这些发现表明了强光与物质耦合在量子材料中的新应用。