Denisdon Simiyon, Senthil Kumar Ponnusamy, Boobalan Chitra, Rangasamy Gayathri
Department of Chemical Engineering, Sri Sivasubramaniya Nadar College of Engineering, Kalavakkam 603110, Tamil Nadu, India.
Centre of Excellence in Water Research (CEWAR), Sri Sivasubramaniya Nadar College of Engineering, Kalavakkam 603110, Tamil Nadu, India.
Langmuir. 2024 Aug 20;40(33):17753-17766. doi: 10.1021/acs.langmuir.4c02192. Epub 2024 Aug 6.
This investigation delved into the field of bifunctional electrocatalyst water splitting, aimed at advancing sustainable energy by addressing the scarcity of efficient nonprecious electrocatalysts capable of facilitating both the hydrogen evolution reaction (HER) and the oxygen evolution reaction (OER). This study focused on nanohybrids consisting of hydrothermally synthesized rGO/MnO/MoS composites and highlighted their efficacy as bifunctional electrocatalysts. The synergistic integration of rGO/MnO/MoS enhanced the surface area, magnified electroactive sites, established a customized conductive arrangement, and provoked the efficiency in splitting of water. The nanohybrid displayed exceptional catalytic performance for the OER and HER, with significantly reduced overpotentials of 208 and 205 mV in 1 M KOH at 10 mA cm current density, respectively. The findings underscore the potential of these cost-effective and environmentally friendly rGO/MnO/MoS nanohybrids in advancing the field of electrocatalysis for renewable energy applications.
本研究深入探讨了双功能电催化剂水分解领域,旨在通过解决能够促进析氢反应(HER)和析氧反应(OER)的高效非贵金属电催化剂的稀缺问题,推动可持续能源发展。本研究聚焦于水热合成的rGO/MnO/MoS复合材料组成的纳米杂化物,并强调了它们作为双功能电催化剂的功效。rGO/MnO/MoS的协同整合增加了表面积,扩大了电活性位点,建立了定制的导电排列,并提高了水分解效率。该纳米杂化物对OER和HER表现出优异的催化性能,在1 M KOH中,10 mA cm电流密度下,过电位分别显著降低至208和205 mV。研究结果强调了这些具有成本效益且环境友好的rGO/MnO/MoS纳米杂化物在推动可再生能源应用的电催化领域的潜力。