Exploring efficient microwave absorbing materials (MAMs) which could convert electromagnetic (EM) energy into thermal energy represents an approbatory vision to reducing EM radiation and interference. Designing of mixed-dimensional structure with multiple interfaces represents the available target to investigate an ideal MAMs, which maximizes the superiority of mixed-dimensional structure in electromagnetic wave absorption (EMWA). Herein, we take full advantage of multiple interfaces engineering of MXene for optimizing the impedance matching to improve EMWA, MXene-based mixed-dimensional structure was designed by incorporating three-dimensional FeC@Carbon layers coated zero-dimensional FeO nanoparticles (NPs) supported two-dimensional MXene nanosheets (MXene/FeO@FeC@Carbon, MFC). The FeO@FeC@C with Core@shell structure arrests the essentially self-restacked of MXene and provides various attenuation mechanisms for the incident electromagnetic waves (EMWs). By regulating the carbonization temperature, the MFC exhibits enhanced EMWA property which is attributed to the characteristic structure and optimized dielectric-magnetic synergy effect. The minimum reflection loss (RL) value of MFC can reach to -64.3 dB with a matching thickness of 1.73 mm. Otherwise, the maximum effective absorption bandwidth (EAB) (RL < -10 dB) reaches 6.42 GHz at only 1.5 mm. Thus, our study refers a novel-fire enlighten to develop excellent mixed-dimensional microwave absorbent based on MXene.