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以硫酸镁水泥为固化剂对黄土固化效果及机理的研究

Investigation on the solidification effect and mechanism of loess utilizing magnesium oxysulfate cement as a curing agent.

作者信息

Yan Xuerui, Xu Qi, Deng Miao, Sun Yanxia, He Xin, Dong Shengde, Ma Luxiang, Hai Chunxi, Zhou Yuan

机构信息

College of Materials and Chemistry & Chemical Engineering, Chengdu University of Technology, Chengdu, China.

College of Materials and Chemistry & Chemical Engineering, Chengdu University of Technology, Chengdu, China.

出版信息

Sci Total Environ. 2024 Nov 15;951:175214. doi: 10.1016/j.scitotenv.2024.175214. Epub 2024 Aug 5.

Abstract

In this study, magnesium oxysulfate cement (MOS) was used as a binder for curing loess. The changes in bulk density, porosity, mineral structure and microstructure of the consolidated loess were systematically studied and verified. The porosity decreased from 40.97 % in pure loess to 28.75 % in 13 % MOS solidified sample. Scanning electron microscopy, energy spectrum analysis and thermogravimetric analysis revealed that the addition of MOS binder resulted in the formation of hydrated products, including Mg(OH), MgO·mSiO·nHO (M-S-H), and 3Mg(OH)·MgSO·8HO (3·1·8 phase), which effectively filled the voids between the grains and facilitated strong bonding among them. After a curing period of 28 days, the compressive strength of loess stabilized with 13 % MOS exhibited an increase to 7.9 MPa. Moreover, following immersion in water for 24 h, the softening coefficient K remained at 0.66. Furthermore, after undergoing five cycles of freeze-thaw cycling, the rate of change in compressive strength R was only 6.3 %. All the results indicate that MOS exhibits promising potential as a binder for soil stabilization applications.

摘要

在本研究中,硫酸镁氧水泥(MOS)被用作黄土固化的粘结剂。系统地研究并验证了固结黄土的堆积密度、孔隙率、矿物结构和微观结构的变化。孔隙率从纯黄土中的40.97%降至13% MOS固化样品中的28.75%。扫描电子显微镜、能谱分析和热重分析表明,添加MOS粘结剂导致形成水合产物,包括Mg(OH)、MgO·mSiO·nHO(M-S-H)和3Mg(OH)·MgSO·8HO(3·1·8相),这些产物有效地填充了颗粒之间的空隙并促进了它们之间的强粘结。养护28天后,13% MOS固化的黄土抗压强度稳定增加至7.9 MPa。此外,在水中浸泡24小时后,软化系数K保持在0.66。此外,经过五次冻融循环后,抗压强度变化率R仅为6.3%。所有结果表明,MOS作为土壤稳定应用的粘结剂具有广阔的潜力。

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