Naguib Hamdy M
Department of Petroleum Applications, Egyptian Petroleum Research Institute (EPRI), Nasr City, 11727, Cairo, Egypt.
Sci Rep. 2024 Aug 6;14(1):18256. doi: 10.1038/s41598-024-68251-8.
The aim is to develop new fiber-reinforced polymer (FRP) water pipe by activating fiber glass (FG) by vinyltriethoxysilane (VS) getting vinylsilane-activated FG (AFG) for filling vinylester (VE) via continuous winding to make a novel VE-AFG composite. The novelty of this work is the activation of fiber glass by vinylsilane as a single filler in vinylester and compounding them via a two-dimensional continuous winding process for the first time. The crosslinking occurred in the AFG/VE/curing agent system after activation. The activated composites increased thermal stability; 25% VE-AGF increased the degradation temperatures at 10%, 25%, and 50% weight loss by 73.3%, 10%, and 7.2%. With the activated 20% composite, values of axial strength, hoop strength, and hardness were developed by 6.3%, 2%, and 8.7%, respectively. The decay resistance to different microorganisms was increased with VE-AFG composites as a result of a sharp decrease in biodegradability percentages. The activated composites are stable toward water absorption; the least percentage was recorded by 25% VE-AFG, which minimized the water absorptivity by more than 62%. The reported characterization sentence approves enhancement of thermal, physical, and mechanical stability of sustainable vinylester-fiber glass composites manufactured by continuous winding; this is recommended for application in water pipe systems.
目的是通过用乙烯基三乙氧基硅烷(VS)活化玻璃纤维(FG),得到乙烯基硅烷活化的FG(AFG),通过连续缠绕填充乙烯基酯(VE),从而开发新型纤维增强聚合物(FRP)水管,制成新型VE-AFG复合材料。这项工作的新颖之处在于首次将乙烯基硅烷作为乙烯基酯中的单一填料活化玻璃纤维,并通过二维连续缠绕工艺将它们复合。活化后,AFG/VE/固化剂体系发生交联。活化后的复合材料提高了热稳定性;25%的VE-AGF使10%、25%和50%失重时的降解温度分别提高了73.3%、10%和7.2%。对于活化后的20%复合材料,轴向强度、环向强度和硬度值分别提高了6.3%、2%和8.7%。由于生物降解率急剧下降,VE-AFG复合材料对不同微生物的抗降解性增强。活化后的复合材料对吸水性稳定;25%的VE-AFG记录的最低百分比将吸水率降低了62%以上。所报道的表征结果证实了通过连续缠绕制造的可持续乙烯基酯-玻璃纤维复合材料的热稳定性、物理稳定性和机械稳定性得到了提高;建议将其应用于水管系统。