二羰基-1κ -μ-氯-2:3κ :-五氯-2κ,3κ -[1(η)-甲苯]二镓(III)钌(I)(-)
Dicarbonyl-1κ -μ-chlorido-2:3κ :-penta-chlorido-2κ ,3κ -[1(η)-toluene]digallium(III)ruthenium(I)(-).
作者信息
Smith Danielle, Harakas George N
机构信息
PO Box 6949, Radford University, Radford, Virginia 24142, USA.
出版信息
IUCrdata. 2024 Jul 9;9(Pt 7):x240657. doi: 10.1107/S2414314624006576. eCollection 2024 Jul.
Abstract
The title compound, [RuGaCl(CH)(CO)] or [(CO)(GaCl)(η-toluene)Ru][GaCl], was isolated from the reaction of GaCl with di-phenyl-silanediol in toluene, followed by the addition of Ru(CO). The compound contains a ruthenium-gallium metal-metal bond with a length of 2.4575 (2) Å.
摘要
标题化合物[RuGaCl(CH)(CO)]或[(CO)(GaCl)(η-甲苯)Ru][GaCl]是通过GaCl与二苯基硅二醇在甲苯中反应，随后加入Ru(CO)分离得到的。该化合物含有一个钌-镓金属-金属键，键长为2.4575 (2) Å。
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