[1-(蒽-9-基甲基)-1,4,7,10-四氮杂环十二烷]氯锌(II)硝酸盐
[1-(Anthracen-9-ylmeth-yl)-1,4,7,10-tetra-aza-cyclododeca-ne]chlorido-zinc(II) nitrate.
作者信息
Ichimaru Yoshimi, Sugiura Kirara, Kato Koichi, Kondo Yuki, Kurihara Masaaki, Jin Wanchun, Imai Masanori, Kurosaki Hiromasa
机构信息
Faculty of Pharmaceutical Sciences, Shonan University of Medical Sciences, 16-48, Kamishinano, Totsuka-ku, Yokohama, Kanagawa, 244-0806, Japan.
College of Pharmacy Kinjo Gakuin University, 2-1723 Omori Moriyamaku Nagoya Aichi 463-8521 Japan.
出版信息
IUCrdata. 2024 Jul 12;9(Pt 7):x240665. doi: 10.1107/S2414314624006655. eCollection 2024 Jul.
In the title salt, [ZnCl(CHN)]NO, the central Zn atom of the complex cation is coordinated in a square-pyramidal arrangement by four nitro-gen atoms from cyclen (1,4,7,10-tetra-aza-cyclo-dodeca-ne) in the basal plane and one chlorido ligand in the apical position. The anthracene group attached to cyclen contributes to the crystal packing through inter-molecular T-shaped π inter-actions. Additionally, the nitrate anion participates in inter-molecular N-H⋯O hydrogen bonds with cyclen.
在标题盐[ZnCl(CHN)]NO中，配合物阳离子的中心Zn原子通过来自环壬四胺（1,4,7,10-四氮杂环十二烷）的四个氮原子在基面以四方锥排列配位，一个氯配体处于顶端位置。连接到环壬四胺上的蒽基团通过分子间T形π相互作用对晶体堆积有贡献。此外，硝酸根阴离子与环壬四胺参与分子间N-H⋯O氢键作用。
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