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[1-(蒽-9-基甲基)-1,4,7,10-四氮杂环十二烷]氯锌(II)硝酸盐

[1-(Anthracen-9-ylmeth-yl)-1,4,7,10-tetra-aza-cyclododeca-ne]chlorido-zinc(II) nitrate.

作者信息

Ichimaru Yoshimi, Sugiura Kirara, Kato Koichi, Kondo Yuki, Kurihara Masaaki, Jin Wanchun, Imai Masanori, Kurosaki Hiromasa

机构信息

Faculty of Pharmaceutical Sciences, Shonan University of Medical Sciences, 16-48, Kamishinano, Totsuka-ku, Yokohama, Kanagawa, 244-0806, Japan.

College of Pharmacy Kinjo Gakuin University, 2-1723 Omori Moriyamaku Nagoya Aichi 463-8521 Japan.

出版信息

IUCrdata. 2024 Jul 12;9(Pt 7):x240665. doi: 10.1107/S2414314624006655. eCollection 2024 Jul.

DOI:10.1107/S2414314624006655
PMID:39108938
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11299653/
Abstract

In the title salt, [ZnCl(CHN)]NO, the central Zn atom of the complex cation is coordinated in a square-pyramidal arrangement by four nitro-gen atoms from cyclen (1,4,7,10-tetra-aza-cyclo-dodeca-ne) in the basal plane and one chlorido ligand in the apical position. The anthracene group attached to cyclen contributes to the crystal packing through inter-molecular T-shaped π inter-actions. Additionally, the nitrate anion participates in inter-molecular N-H⋯O hydrogen bonds with cyclen.

摘要

在标题盐[ZnCl(CHN)]NO中，配合物阳离子的中心Zn原子通过来自环壬四胺（1,4,7,10-四氮杂环十二烷）的四个氮原子在基面以四方锥排列配位，一个氯配体处于顶端位置。连接到环壬四胺上的蒽基团通过分子间T形π相互作用对晶体堆积有贡献。此外，硝酸根阴离子与环壬四胺参与分子间N-H⋯O氢键作用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4386/11299653/e2b0638d890a/x-09-x240665-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4386/11299653/2a0d25cdcab0/x-09-x240665-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4386/11299653/42403a45e02b/x-09-x240665-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4386/11299653/e2b0638d890a/x-09-x240665-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4386/11299653/2a0d25cdcab0/x-09-x240665-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4386/11299653/42403a45e02b/x-09-x240665-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4386/11299653/e2b0638d890a/x-09-x240665-fig3.jpg

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