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双[5-(蒽-9-基甲基)-1,5,9-三氮杂环十二烷-1-鎓]四氯锌酸盐

Bis[5-(anthracen-9-ylmeth-yl)-1,5,9-tri-aza-cyclododecan-1-ium] tetra-chlorido-zincate.

作者信息

Ichimaru Yoshimi, Kato Koichi, Jin Wanchun, Kurihara Masaaki, Kurosaki Hiromasa

机构信息

Faculty of Pharmaceutical Sciences, Shonan University of Medical Sciences, 16-48, Kamishinano, Totsuka-ku, Yokohama, 244-0806, Japan.

College of Pharmacy Kinjo Gakuin University, 2-1723 Omori Moriyamaku Nagoya 463-8521 Japan.

出版信息

IUCrdata. 2025 May 2;10(Pt 5):x250356. doi: 10.1107/S2414314625003566. eCollection 2025 May.

DOI:10.1107/S2414314625003566
PMID:40487511
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12142395/
Abstract

A crystalline salt comprising two monoprotonated polyamine ligands and one tetra-chloro-zincate(II) anion was prepared, (CHN)[ZnCl], and its crystal structure was analyzed and compared with those of structurally related compounds bearing different macrocyclic frameworks and pendant arms. The protonated nitro-gen atoms engaged in intra-molecular hydrogen bonding with other nitro-gen atoms within the macrocyclic ring. In the crystal, the pendant anthracene groups participated in inter-molecular π-π and C-H⋯π inter-actions, contributing to crystal cohesion.

摘要

制备了一种包含两个单质子化多胺配体和一个四氯锌酸根（II）阴离子的结晶盐，即(CHN)[ZnCl]，并对其晶体结构进行了分析，还与具有不同大环骨架和侧链的结构相关化合物的晶体结构进行了比较。质子化的氮原子与大环环内的其他氮原子形成分子内氢键。在晶体中，侧链蒽基团参与分子间的π-π和C-H⋯π相互作用，有助于晶体凝聚。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5140/12142395/32b38c8ca739/x-10-x250356-fig5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5140/12142395/60e86c83a3b3/x-10-x250356-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5140/12142395/1015e31354d8/x-10-x250356-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5140/12142395/5657e2924fe7/x-10-x250356-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5140/12142395/73ae8a77edfe/x-10-x250356-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5140/12142395/32b38c8ca739/x-10-x250356-fig5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5140/12142395/60e86c83a3b3/x-10-x250356-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5140/12142395/1015e31354d8/x-10-x250356-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5140/12142395/5657e2924fe7/x-10-x250356-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5140/12142395/73ae8a77edfe/x-10-x250356-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5140/12142395/32b38c8ca739/x-10-x250356-fig5.jpg

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本文引用的文献

1
Design, Synthesis, and Characterization of 1-(Anthracen-9-ylmethyl)-1,5,9-triazacyclododecane (Ant-[12]aneN3) and Its DNA Photocleavage Activity.1-(蒽-9-基甲基)-1,5,9-三氮杂环十二烷（Ant-[12]aneN3）的设计、合成与表征及其DNA光裂解活性
Chem Pharm Bull (Tokyo). 2025;73(2):103-107. doi: 10.1248/cpb.c24-00705.
2
[1-(Anthracen-9-ylmeth-yl)-1,4,7,10-tetra-aza-cyclododeca-ne]chlorido-zinc(II) nitrate.[1-(蒽-9-基甲基)-1,4,7,10-四氮杂环十二烷]氯锌(II)硝酸盐
IUCrdata. 2024 Jul 12;9(Pt 7):x240665. doi: 10.1107/S2414314624006655. eCollection 2024 Jul.
3
Aqua-(1,4,7,10-tetra-aza-cyclo-dodeca-ne)zinc(II) bis-(perchlorate).
水合 -（1,4,7,10 - 四氮杂环十二烷）锌（II）双（高氯酸盐）
IUCrdata. 2021 Apr 20;6(Pt 4):x210397. doi: 10.1107/S2414314621003977. eCollection 2021 Apr.