Moroni Marco, Coccia Clarissa, Malavasi Lorenzo
Department of Chemistry and INSTM, University of Pavia, Via Taramelli 12, 27100 Pavia, Italy.
Chem Commun (Camb). 2024 Aug 27;60(70):9310-9327. doi: 10.1039/d4cc03314k.
Chiral 2D and quasi-2D hybrid organic-inorganic perovskites (HOIPs) are emerging as promising materials for a variety of applications principally related to optoelectronics and spintronics, thanks to the combined benefits deriving from both the chiral cation and the perovskite structure. Since its recent birth, this research field is tremendously growing, focalizing on the chemical composition tuning to unveil its influence on the related functional properties as well as on developing devices for practical applications. In this review, we focused on the properties of 2D and quasi-2D chiral HOIPs, firstly providing an overview on their chiroptical behaviour followed by their potential exploitation in devices investigated so far for various applicative fields.
手性二维和准二维有机-无机杂化钙钛矿(HOIPs)正成为有前途的材料,可用于多种主要与光电子学和自旋电子学相关的应用,这得益于手性阳离子和钙钛矿结构带来的综合优势。自该研究领域近期诞生以来,它一直在迅猛发展,专注于化学成分的调整,以揭示其对相关功能特性的影响,并开发实际应用的器件。在这篇综述中,我们聚焦于二维和准二维手性HOIPs的特性,首先概述它们的手性光学行为,接着介绍它们在目前已针对各种应用领域进行研究的器件中的潜在应用。