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合成亲脂性维生素 C 并评价其在葵花籽油煎炸中的抗氧化性能。

Synthesis of lipophilic vitamin C and evaluation of its antioxidant performance in sunflower seed oil frying.

机构信息

Key Laboratory for Animal Nutrition and Feed Science of Hubei Province, Wuhan Polytechnic University, Wuhan 430000, China.

Hubei Key Laboratory of Biomass Fibers and Eco-dyeing & Finishing, College of Chemistry and Chemical Engineering, Wuhan Textile University, Wuhan 430200, China.

出版信息

Food Chem. 2024 Dec 1;460(Pt 3):140727. doi: 10.1016/j.foodchem.2024.140727. Epub 2024 Aug 2.

Abstract

The present study involved the synthesis and analysis of a lipophilic form of vitamin C, namely tetrabutyryl vitamin C ester (TVCE). TVCE is synthesized by a simple one-step method, combining the advantages of VC and butyric acid. Its antioxidant efficacy on sunflower seed oil frying was evaluated by assessing lipid oxidation parameters including peroxide number (POV), carbonyl number (CV), and paraniline number (pAV). Furthermore, changes in the fatty acid composition of the oil were monitored using techniques such as infrared spectroscopy (IR), nuclear magnetic resonance (NMR), and gas chromatography (GC). The findings demonstrated that lipophilic vitamin C exhibited superior protection against oxidation during frying compared to vitamin E, suggesting that it may be an effective fat-soluble antioxidant. The study provides a new field for the utilization of vitamin C and a new idea for the development of efficient antioxidants.

摘要

本研究涉及脂溶性维生素 C 形式的合成和分析,即维生素 C 丁酯(TVCE)。TVCE 通过简单的一步法合成,结合了 VC 和丁酸的优点。通过评估包括过氧值(POV)、羰基值(CV)和对氨基值(pAV)在内的脂质氧化参数,评估了 TVCE 对葵花籽油煎炸的抗氧化效果。此外,还使用红外光谱(IR)、核磁共振(NMR)和气相色谱(GC)等技术监测油中脂肪酸组成的变化。研究结果表明,脂溶性维生素 C 在煎炸过程中表现出比维生素 E 更好的抗氧化保护作用,这表明它可能是一种有效的脂溶性抗氧化剂。该研究为维生素 C 的利用提供了一个新的领域,为高效抗氧化剂的开发提供了一个新的思路。

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